聚合物/纳米黏土复合材料的研究进展
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摘要
简述了纳米黏土的结构特点,常见的有机化改性方法,介绍了可插层黏土的有机单体和聚合物类型。综述了聚合物/纳米黏土复合材料的制备方法,介绍了单体溶液插层、聚合物水溶液插层、乳液插层等溶液插层方法和单体熔融插层、聚合物熔融插层、熔融挤出插层等熔融插层方法。总结了聚合物/纳米黏土复合材料的国内外研究进展与应用现状,主要在汽车工业、包装材料、环境友好材料、新型工程材料等领域得到了广泛应用。
This paper describes the structural characteristics and organic modification of the nano-clay. It introduces the organic monomers and polymers for intercalated clay. It reviews the preparation of polymer/nanoclay composites including intercalation of monomer solution,polymer water solution,and emulsion as well as melting intercalation of monomer,polymer and extrusion. The research progress and application of the composites in China and abroad are summarized,covering automobile,packing,environmentally-friendly materials,and novel engineering materials.
This paper describes the structural characteristics and organic modification of the nano-clay. It introduces the organic monomers and polymers for intercalated clay. It reviews the preparation of polymer/nanoclay composites including intercalation of monomer solution,polymer water solution,and emulsion as well as melting intercalation of monomer,polymer and extrusion. The research progress and application of the composites in China and abroad are summarized,covering automobile,packing,environmentally-friendly materials,and novel engineering materials.
引文
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[38]Kerber M L,Gorbunova I Y,Shibryaeva L D,et al. Effect of montmorillonite on polypropylene crystallization[J]. Russ J Appl Chem,2017,90(3):435-439.
[39]Yang Jintao,Fan Hong,Bu Zhiyang,et al. Influence of clay and predispersion method on the structure and properties of polystyrene(PS)-clay nanocomposites[J]. Polym Eng Sci,2009,49(10):1937-1944.
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[44]Vidotti S E,Chinellato A C,Hu Guohua,et al. Effect of an organo-modified montmorillonite on the barrier properties of PET nanocomposites using a polyester ionomer as a compatibilizing agent[J]. Mat Res,2017,20(3):22-27.
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[51]功玉.新型PPR管材生产线通过鉴定[J].塑料科技,2007,35(11):36-37.
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[2]Momani B,Sen Mani,Endoh M,et al. Temperature dependent intercalation and self–exfoliation of clay/polymer nanocomposite[J]. Polymer,2016,93:204-212.
[3]范家起,尚文宇,阳明书,等.聚合物/粘土纳米复合材料中的黏土有机化[J].高分子通报,2016(9):227-240.
[4] Gul S,Kausar A,Muhammad B,et al. Research progress on properties and applications of polymer/clay nanocomposite[J].J Macromol Sci A,2016,55(7):684-703.
[5]范家起,马永梅,漆宗能.聚合物/粘土纳米复合材料的近期进展[J].高分子通报,2013(9):18-21.
[6]陈广新,郝广杰,郭天瑛,等.聚合物/层状硅酸盐纳米复合材料的性能[J].高分子通报,2002(2):61-66.
[7]Pavlidou S,Papaspyrides C D. A review on polymer–layered silicate nanocomposites[J]. Prog Polym Sci,2008,33(12):1119-1198.
[8]吴刘锁,何素芹,辛建泉,等.聚合物/蒙脱土纳米复合材料的研究进展[J].塑料科技,2009,37(2):82-87.
[9]徐文,武小雷,孙伟福.聚合物/层状矿物纳米复合材料的研究进展[J].硅酸盐学报,2016,44(5):769-779.
[10]Pan Lingying,Zhan Maosheng,Wang Kai. High-temperatureresistant polyimide/montmorillonite nanocomposite foams by solid blending[J]. Polym Eng Sci,2011,51(7):1397-1403.
[11]李微微,陈涛,雷新荣.高分子/层状硅酸盐纳米复合材料的研究应用现状及发展前景[J].安徽化工,2006,32(1):7-10.
[12]陆银平,张玉德,刘钦甫,等.纳米粘土的制备及应用研究进展[J].化工新型材料,2009,37(10):8-10.
[13]王春伟,郑素群,周军贤.层状粘土纳米材料的特性、加工及应用评述[J].中国非金属矿工业导刊,2008,72(6):3-8.
[14]陈海群,徐义荣,赵银芝.蒙脱土的表面修饰[J].化工矿物与加工,2008,37(8):35-38.
[15]蒲侠,张兴华,周彦豪,等.聚合物/纳米粘土插层复合材料的研究进展[J].工程塑料应用,2004,32(3):67-70.
[16]浦敏锋,刘梅堂.聚合物/粘土纳米复合材料中有机改性剂的研究进展[J].高分子材料科学与工程,2010,26(12):168-172.
[17]He Wentao,Liao Shengtao,Xiang Yushu,et al. Structure and properties study of PA 6 nanocomposites flame retarded by aluminium salt of diisobutylphosphinic acid and different organic montmorillonites[J]. Polymer,2018,10(3):312-316.
[18]Xu Bo,Zheng Qiang. Effects on preparation of polymerlayered silicate nanocompositesby melt-intercalation[J].Polym Mater Sci,2005,21(1):43-47.
[19]佘希林,宋国君,王俊霞,等.插层法制备聚合物/粘土纳米复合材料及其应用进展[J].高分子材料科学与工程,2003,19(1):32-35.
[20]Yu Wenxue,Zhao Zhudi,Zheng Weitao,et al. Structural characteristics of poly(vinylidene fluoride)/clay nanocomposites[J]. Mater Lett,2008,62(4/5):747-750.
[21]Bhattacharya M,Biswas S,Bhowmick A K. Permeation characteristicsandmodelingofbarrierpropertiesof multifunctional rubber nanocomposites[J]. Polymer,2011,52(7):1562-1576.
[22]戈明亮,阚长华,徐卫兵.聚合物/粘土纳米复合材料的插层制备方法[J].材料导报,2003,17(9):114-116.
[23]Zhu Shijie,Okazaki M,Usuki A,et al. Tensile and fatigue behavior in clay reinforced nylon 6 nanocomposites[J]. J Soc Mater Sci Jap,2009,58(12):969-974.
[24]Uhl F M,Webster D C,Davuluri S P,et al. UV curable epoxy acrylate–clay nanocomposites[J]. Eur Polym J,2006,42(10):2596-2605.
[25]Dar B A,Shrivastava V,Bowmik A,et al. An expeditious N,Ndibenzylation of anilines under ultrasonic irradiation conditions using low loading Cu(Ⅱ)-clay heterogeneous catalyst[J].Tetrahedron Lett,2015,56(1):136-141.
[26]张径,杨玉昆.插层法悬浮聚合制PMMA蒙脱土纳米复合材料[J].高分子学报,2001(1):79-83.
[27]Shen Zhiqi,Simon G P,Cheng Yibing. Nanocomposites of poly(methyl methacrylate)and organically modified layered silicates by melt intercalation[J]. J Appl Polym Sci,2004,92(4):2101-2115.
[28]雷西萍,王栋东.乳液聚合法制备有机改性高岭土/聚苯胺复合材料及其性能研究[J].材料导报,2012,26(2):128-131.
[29]王益庆,张惠峰,张立群,等.粘土/天然橡胶纳米复合材料的制备及性能[J].合成橡胶工业,2005,28(2):135-139.
[30]Salahuaddin N A. Layered silicate/epoxy nanocomposites:synthesis,characterization and properties[J]. Polym Adv Technol,2004,15(5):251-259.
[31]刘明华,陈光明,漆宗能,等.聚酰胺6/粘土纳米复合材料结晶行为研究进展[J].高分子通报,2006,84(10):98-102.
[32]Usuki A,Koiwai A,Kojima Y,et al. Interaction of nylon 6-clay surface and mechanical properties of nylon 6-clay hybrid[J].J Appl Polym Sci,2010,55(1):119-123.
[33]江梅,范家起,漆宗能,等.不同有机化蒙脱土对聚丙烯/蒙脱土纳米复合材料结构和性能的影响[J].高等学校化学学报,2008,29(7):1483-1487.
[34]漆宗能,尚文宇.聚合物/层状硅酸盐纳米复合材料理论与实践[M].北京:化学工业出版社,2002:31-47.
[35]Richard A,Giannelis E P. Lattice model of polymer melt intercalation in organically-modified layered silicates[J].Macromolecules,1997,30(25):7990-7999.
[36]Li Zhipeng,Gong Jing,Du Sen,et al. Nano-montmorillonite modified foamed paste with high volume fly ash binder[J].Rsc Adv,2017,7(16):9803-9812.
[37]Hamidi S,Marandi S M. Clay concrete and effect of clay minerals types on stabilized soft clay soils by epoxy resin[J].Appl Clay Sci,2018,151:92-101.
[38]Kerber M L,Gorbunova I Y,Shibryaeva L D,et al. Effect of montmorillonite on polypropylene crystallization[J]. Russ J Appl Chem,2017,90(3):435-439.
[39]Yang Jintao,Fan Hong,Bu Zhiyang,et al. Influence of clay and predispersion method on the structure and properties of polystyrene(PS)-clay nanocomposites[J]. Polym Eng Sci,2009,49(10):1937-1944.
[40]Gawad A A,Esawi A M K,Ramadan A R. Structure and propertiesofnylon6–claynanocomposites:effectof temperature and reprocessing[J]. J Mater Sci,2010,45(24):6677-6684.
[41]瞿雄伟,罗艳红,丁会利,等.聚氯乙烯/粘土熔融插层复合材料的研究[J].材料工程,2002(4):9-23.
[42]Loo L S,Gleason K K. Investigation of polymer and nanoclay orientation distribution in nylon/montmorillonite nanocomposite[J]. Polymer,2004,45(17):5933-5939.
[43]Tang Yong,Hu Yuan,Song Lei,et al. Preparation and thermal stability of polypropylene/montmorillonite nano-composites[J]. Polym Degrad Stab,2003,82(1):127-131.
[44]Vidotti S E,Chinellato A C,Hu Guohua,et al. Effect of an organo-modified montmorillonite on the barrier properties of PET nanocomposites using a polyester ionomer as a compatibilizing agent[J]. Mat Res,2017,20(3):22-27.
[45]崔文广,高岩磊,张雪红. PA 6/PA 6-g-MAH/云母复合材料的增韧研究[J].塑料科技,2011,39(7):58-60.
[46]Jang B N,Wilkie K A. The effect of clay on the thermal degradation of polyamide 6 in polyamide 6/clay nanocomposites[J]. Polymer,2005,46(10):3264-3274.
[47]马永梅,范家起.浅谈高分子/粘土纳米复合材料市场应用及发展[J].纳米科技与产业,2003,117(8):67-71.
[48]Dahiya J B,Rathi S,Bockhorn H,et al. The combined effect of organic phoshphinate/ammonium polyphosphate and pentaerythritol on thermal and fire properties of polyamide 6-clay nano-composites[J]. Polym Degrad Stab,2012,97(8):1458-1465.
[49]Bineesh K V,Cho D R,Kim S Y,et al. Vanadia-dopedtitaniapillared montmorillonite clay for the selective catalytic oxidation of H2S[J]. Catal Commun,2008,9(10):2040-2043.
[50]Bouchenafa-Sa?b N,Khouli K,Mohammedi O. Preparation and characterization of pillared montmorillonite:application in adsorption of cadmium[J]. Desalination,2007,217(1):282-290.
[51]功玉.新型PPR管材生产线通过鉴定[J].塑料科技,2007,35(11):36-37.
[52]Mondal D,Bhowmick B,Mollick M R,et al. Antimicrobial activity and biodegradation behavior of poly(butylene adipate-co-terephthalate)/clay nanocomposites[J]. J Appl Polym Sci,2014,131(7):2113-2124.
[53]马壮,郜世喜,李智超.坡缕石性能及应用现状[J].硅酸盐通报,2011,30(3):583-587.
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