石墨烯等离激元增强红外光谱
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  • 英文篇名:Graphene plasmon enhanced infrared spectroscopy
  • 作者:吴晨晨 ; 郭相东 ; 胡海 ; 杨晓霞 ; 戴庆
  • 英文作者:Wu Chen-Chen;Guo Xiang-Dong;Hu Hai;Yang Xiao-Xia;Dai Qing;Division of Nanophotonics, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology;Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences;
  • 关键词:石墨烯 ; 等离激元 ; 表面增强光谱 ; 红外光谱
  • 英文关键词:graphene;;plasmon;;surface enhanced spectroscopy;;infrared spectroscopy
  • 中文刊名:WLXB
  • 英文刊名:Acta Physica Sinica
  • 机构:国家纳米科学中心中国科学院纳米科学卓越创新中心;中国科学院大学材料与光电研究中心;
  • 出版日期:2019-07-23
  • 出版单位:物理学报
  • 年:2019
  • 期:v.68
  • 基金:国家重点基础研究发展计划(批准号:2015CB932400);; 国家重点研发计划(批准号:2016YFA0201600);; 国家自然科学基金(批准号:11674073,11504063,11704085);; 中国科学院前沿科学重点研究项目(批准号:QYZDB-SSW-SLH021);中国科学院重点部署项目(批准号:ZDBS-SSW-JSC002),中国科学院青年创新促进会和中国科学院创新交叉团队项目(批准号:JCTD-2018-03)资助的课题~~
  • 语种:中文;
  • 页:WLXB201914016
  • 页数:16
  • CN:14
  • ISSN:11-1958/O4
  • 分类号:214-229
摘要
红外光谱能够精准反映分子振动的信息,是表征材料成分和结构的重要手段.但是纳米尺度材料与微米尺度红外光波长之间约三个数量级的尺寸失配导致两者之间相互作用十分微弱,无法直接进行红外光谱表征.因此如何获得微量纳米材料的红外光谱信息成为了近年来红外光谱领域面临的关键挑战.等离激元能够将光场压缩实现局域光场增强,从而增强光与物质的相互作用.其中石墨烯等离激元因其具有高光场压缩、电学动态可调和低本征衰减等优点,为表面增强红外光谱提供了重要的解决方案.本文首先从不同材料体系出发介绍了红外等离激元,在此基础上从石墨烯的基本性质出发总结石墨烯等离激元及其在表面增强红外光谱上的优势,并重点介绍了石墨烯等离激元增强红外光谱的最新进展和应用,包括单分子层生物化学探测、气体识别和折射率传感等.最后对石墨烯等离激元增强红外光谱的下一步发展方向和应用前景进行了展望.
        Infrared spectroscopy can accurately reflect the information of molecular vibration, and it is an important technology to characterize the composition and structure of materials. However, since the interaction between nanomaterials and infrared light is very weak due to the significant size mismatch, it is challenging to obtain the spectral information of nanomaterials in the field of infrared spectroscopy. The plasmon is a collective electron oscillation on the surface of the material inducing by the incident light, and it has excellent light field confinement, which can significantly enhance the interaction between light and nanomaterials. Graphene plasmon has prominent properties, such as high light field confinement, dynamic adjustment, and low intrinsic attenuation. Therefore it is an important solution to enhance the infrared absorption of nanomaterials. This article systematically introduces the infrared plasmon materials system. Then it summarizes the characteristics of graphene plasmon and their advantages on surface enhanced infrared spectroscopy, and it emphasizes the recent important researches and applications of graphene plasmon enhanced infrared spectroscopy in the world,including single molecular layer biochemical detection, gas identification, refractive index sensing, etc. Further prospects for the development and potential applications of graphene plasmon enhanced infrared spectroscopy are also demonstrated.
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