表面活性剂辅助的水相剥离法制备石墨烯研究进展
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摘要
表面活性剂辅助水相剥离法是一种制备较高质量石墨烯的方法。概述了表面活性剂辅助的水相剥离方法的技术优势,包括方法绿色环保、便于规模化、所得石墨烯质量高和产量大等特点。在此基础上,重点综述了近年来不同种类表面活性剂辅助水相剥离石墨烯的研究进展,其中离子型表面活性剂辅助剥离石墨烯,包括烷基阴离子表面活性剂辅助剥离石墨、胆盐类表面活性剂辅助剥离石墨、芘衍生物辅助剥离石墨、阳离子型表面活性剂辅助剥离石墨等;非离子性表面活性剂辅助剥离石墨,包括聚乙烯吡咯烷酮辅助剥离石墨、聚醚表面活性剂辅助剥离石墨、聚乙烯基咪唑类高分子辅助水相剥离石墨等。针对各种形式的表面活性剂辅助水相剥离石墨方法,分别从制备流程、表面活性剂物理化学性能、制得的石墨烯的结构与性能等方面进行了归纳与对比。最后展望了液相剥离制备石墨烯方法在未来的发展方向。
Surfactant-assisted aqueous phase exfoliation is an effective method for preparing high-quality graphene. The advantages of surfactant-assisted aqueous phase exfoliation method were summarized, including environmentally-friendly, suitable for large-scale production and can easily obtained high quality and high yield of graphene. On this basis, the research progress of different surfactant-assisted aqueous phase exfoliation methods in recent years was reviewed. Among them, ionic surfactant-assisted exfoliation of graphene, including alkyl anionic surfactant-assisted exfoliation of graphite, biliary surfactant-assisted exfoliation of graphite and pyrene derivative-assisted exfoliation of graphite were emphasized. Non-ionic surfactant assisted graphene stripping, including polyvinyl pyrrolidone assisted graphite stripping, polyether surfactant assisted graphite stripping and polyvinyl imid-azole polymer assisted graphite stripping. The preparation process, physicochemical properties of surfactants and the structure and properties of prepared graphene were summarized and compared for various surfactant-assisted aqueous phase stripping methods. Finally, we prospected the development trend of liquid phase exfoliation method for preparing graphene.
Surfactant-assisted aqueous phase exfoliation is an effective method for preparing high-quality graphene. The advantages of surfactant-assisted aqueous phase exfoliation method were summarized, including environmentally-friendly, suitable for large-scale production and can easily obtained high quality and high yield of graphene. On this basis, the research progress of different surfactant-assisted aqueous phase exfoliation methods in recent years was reviewed. Among them, ionic surfactant-assisted exfoliation of graphene, including alkyl anionic surfactant-assisted exfoliation of graphite, biliary surfactant-assisted exfoliation of graphite and pyrene derivative-assisted exfoliation of graphite were emphasized. Non-ionic surfactant assisted graphene stripping, including polyvinyl pyrrolidone assisted graphite stripping, polyether surfactant assisted graphite stripping and polyvinyl imid-azole polymer assisted graphite stripping. The preparation process, physicochemical properties of surfactants and the structure and properties of prepared graphene were summarized and compared for various surfactant-assisted aqueous phase stripping methods. Finally, we prospected the development trend of liquid phase exfoliation method for preparing graphene.
引文
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[32]YANG H,HERNANDEZ Y,SCHLIERF A,et al.A simple method for graphene production based on exfoliation of graphite in water using 1-pyrenesulfonic acid sodium salt[J].Carbon,2013,53(3):357-365.
[33]NOTLEY S M,Highly concentrated aqueous suspensions of graphene through ultrasonic exfoliation with continuous surfactant addition[J].Langmuir,2012,28(40):14110-14113.
[34]BOURLINOS A B,GEORGAKILAS V,ZBORIL R,et al.Aqueous-phase exfoliation of graphite in the presence of polyvinylpyrrolidone for the production of water-soluble graphenes[J].Solid state communications,2009,149(47-48):2172-2176.
[35]杨青.石墨烯分散体系的制备及其性能研究[D].上海:华东理工大学,2017.YANG Qing.Preparation and performance of grapheme dispersions[D].Shanghai:East China University of Science and Technology,2017.
[36]GUARDIA L,FERNáNDEZ-MERINO M J,PAREDESJ I,et al.High-throughput production of pristine graphene in an aqueous dispersion assisted by non-ionic surfactants[J].Carbon,2011,49(5):1653-1662.
[37]CUI J,SONG Z,XIN L,et al.Exfoliation of graphite to few-layer graphene in aqueous media with vinylimidazole-based polymer as high-performance stabilizer[J].Carbon,2016,99:249-260.
[38]KABE R,FENG X L,ADACHI C,et al.Exfoliation of graphite into graphene in polar solvents mediated by amphiphilic hexa-peri-hexabenzocoronene[J].Chemistry a sian journal,2014,9(11):3125-3129.
[39]WAJID A S,DAS S,IRIN F,et al.Polymer-stabilized graphene dispersions at high concentrations in organic solvents for composite production[J].Carbon,2012,50(2):526-534.
[40]BANG G S,SO H M,LEE M J,et al.Preparation of graphene with few defects using expanded graphite and rose bengal[J].Journal of materials chemistry,2012,22(11):4806-4810.
[41]XU L X,MCGRAW J W,FAN G,et al.Production of high-concentration graphene dispersions in low-boilingpoint organic solvents by liquid-phase noncovalent exfoliation of graphite with a hyperbranched polyethylene and formation of graphene/ethylene copolymer composites[J].The journal of physical chemistry C,2013,117(20):10730-10742.
[42]XIAO W J,SUN Z Y,CHEN S,et al.Ionic liquid-stabilized graphene and its use in immobilizing a metal nanocatalyst[J].RSC advances,2012(2):8189-8193.
[43]NUVOLI D,VALENTINI L,ALZARI V.High concentration few-layer graphene sheets obtained by liquid exfoliation of graphite in ionic liquid[J].The journal of material chemistry,2011(21):3428-3431.
[44]KHAN U,O'NEILL A,LOYTA M,et al.High-concentration solvent exfoliation of graphene[J].Small,2010,6(7):864-871.
[45]LIU C Q,HU G X,GAO H Y.Preparation of few-layer and single-layer by exfoliation of expandable graphite in supercritical N,N-dimethylformamide[J].The journal of supercritical fluids,2012,63:99-104.
[46]GAO Y H,SHI W,WANG W C,et al.Ultrasonic-assisted production of graphene with high yield in supercritical CO2 and its high electrical conductivity film[J].Industrial&engineering chemistry research,2014,53:2839-2845.
[47]HERNANDEZ Y,NICOLOSI V,LOTYA M,et al.Highyield production of graphene by liquid-phase exfoliation of graphite[J].Nature nanotechnology,2008,3(9):563-568.
[48]NARAYAN R,KIM S O.Surfactant mediated liquid phase exfoliation of graphene[J].Nano convergence,2015,2(1):20.
[49]洪庭旭.界面活性剂溶液湿润疏水表面之行为[D].台湾:台湾中央大学,1916.HONG Ting-xu.Wetting behavior of surfactant solutions on hydrophobic surface:copper and telfon[D].Taiwan:National Central University,1916.
[50]DU W,JIANG X,ZHU L.From graphite to graphene:direct liquid-phase exfoliation of graphite to produce single-and few-layered pristine graphene[J].Journal of materials chemistry A,2013,36(1):10592-10606.
[51]BEPETE G,ANGLARET E,ORTOLANI L,et al.Surfactant-free single-layer graphene in water[J].Nature chemistry,2017,9(4):347-352.
[52]CHEN J P,SHI W L,DONG F,et al.A binary solvent system for improved liquid phase exfoliation of pristine grapheme materials[J].Carbon,2015,94:405-411.
[53]祁帅,黄国强.超声波辅助二元溶剂剥离制备石墨烯[J].材料导报A,2017,31(5):72-76.QI Shuai,HUANG Guo-qiang.Preparation of graphene by ultrasonic-assisted exfoliation of graphite in binary solvents[J].Materials review A,2017,31(5):72-76.
[54]PERUMAL S,LEE H M,CHEONG I W.Highconcentration graphene dispersion stabilized by block copolymers in ethanol[J].Journal of colloid and interface science,2017,497:359-367.
[2]BOLOTIN K I,SIKES K J,JIANG Z,et al.Ultrahigh electron mobility in suspended graphene[J].Solid state communications,2008,146(9-10):351-355.
[3]NAIR R R,BLAKE P,GRIGOREKO A N,et al.Fine structure constant defines visual transparency of graphene[J].Science,2008,320(5881):1308.
[4]BALANDIN A A,GHOSH S,BAO W,et al.Superior thermal conductivity of single-layer graphene[J].Nano letters,2008,8(3):902-907.
[5]SANCHEA-YAMAGSHI J D,LUO J Y,YOUNG A F,et al.Helical edge states and fraction quantum hall effect in a graphene electron-hole bilayer[J].Nature nanotechnology,2017,12(2):118-122.
[6]RANGAPPA D,SONE K,WANG M S,et al.Rapid and direct conversion of graphite crystals into high-yielding,good-quality graphene by supercritical fluid exfoliation[J].Chemistry(a european jounral),2010,16(22):6488-6494.
[7]SCHEDIN F,GEIM A K,MOROZO S V,et al.Detection of individual gas molecules adsorbed on graphene[J].Nature materials,2007,6(9):652-655.
[8]CHEN D,FENG H,LI J.Graphene oxide:preparation,functionalization,and electrochemical applications[J].Chemical reviews,2012,112(11):6027-6053.
[9]WU J,AGRAWAL M,BECERRIL H A,et al.Organic light-emitting diodes on solution-processed graphene transparent electrodes[J].ACS nano,2010,4(1):43-48.
[10]KIM J,LEE M S,JEON S,et al.Highly transparent and stretchable field-effect transistor sensors using graphenenanowire hybrid nanostructures[J].Advanced materials,2015,27(21):3292-3297.
[11]YANG J,ZHANG E,LI X,et al.Direct reduction of graphene oxide by Ni foam as a high-capacitance super capacitor electrode[J].ACS applied material and interfaces,2016,8(3):2297-2305.
[12]袁美蓉,赵方辉,刘伟强,等.超级电容器用石墨烯极片的制备和性能[J].功能材料,2013,19(44):2810-2818.YUAN Mei-rong,ZHAO Fang-hui,LIU Wei-qiang,et al.Preparation and properties of graphene for super capacitor application[J].Journal of functional material,2013,19(44):2810-2818.
[13]ZUO Z,KIM T Y,KHOLMANO I,et al.Ultra-light hierarchical graphene electrode for binder-free super capacitors and lithium-ion battery anodes[J].Small,2015,11(37):4922-4930.
[14]YI M,SHEN Z.A review on mechanical exfoliation for the scalable production of graphene[J].Journal of materials chemistry A,2015,3(22):11700-11715.
[15]LI P,XU Z,LIU Z,et al.An iron-based green approach to1-h production of single-layer grapheme oxide[J].Nature communication,2015,6:5716-5724.
[16]LIU N,LEI F,DAI B,et al.Universal segregation growth approach to wafer-size graphene from non-noble metals[J].Nano letters,2011,11(1):297-303.
[17]PARVEZ K,LI R,PUNIREDD S R,et al.Electrochemically exfoliated graphene as solution-processable,highly conductive electrodes for organic electronics[J].ACSnano,2013,7(4):3598-3606.
[18]COLEMAN N J.Liquid-phase exfoliation of nanotubes and graphene[J].Advanced functional materials,2009,19(23):3680-3695.
[19]张艳,戴雷,黄友元,等.石墨烯水性复合防腐涂料的研究进展[J].表面技术,2017,46(10):42-48.ZHANG Yan,DAI Lei,HUANG You-yuan,et al.Research on graphene-based waterborne composite anticorrosive coatings[J].Surface technology,2017,46(10):42-48.
[20]程红红,刘栓,王娟,等.石墨烯防腐涂层对油罐沉积水的防腐机制研究[J].表面技术,2017,46(11):83-89.CHENG Hong-hong,LIU Shuan,WANG Juan,et al.Anticorrosion mechanism of graphene anticorrosive coating in oil tank sedimentary water[J].Surface technology,2017,46(11):83-89.
[21]陶睿,刘朝辉,班国东,等.新型碳系吸波涂层材料研究进展[J].表面技术,2017,46(3):165-171.TAO Rui,LIU Zhao-hui,BAN Guo-dong,et al.Research progress of novel carbon series absorbing coating materials[J].Surface technology,2017,46(3):165-171.
[22]甘贵江,奚新国,姚冠新.石墨烯对铜基制动材料的性能影响[J].表面技术,2017,46(6):84-89.GAN Gui-jiang,XI Xin-guo,YAO Guan-xin.Effect of graphene on properties of copper-based brake materials[J].Surface technology,2017,46(6):84-89.
[23]NOVOSELOV K S,FAL'KOVí,COLOMBO P R,et al.A roadmap for graphene[J].Nature,2012,490:192-200.
[24]LOTYA M,HERNANDEZ Y,KING P J,et al.Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions[J].Journal of American Chemistry Society,2009,131(10):3611-3620.
[25]SMITH R J,LOYTA M,COLEMAN J N.The importance of repulsive potential barriers for the dispersion of graphene using surfactants[J].New journal of physics,2010,12(12):125008.
[26]MING T,LIN CT,KONG J.Re-dispersible graphene dry powder:United States,US 2017/0050856 A1[P].2017-02-23.
[27]RAMALINGAM P,PUSULURI S T,PERIASAMY S,et al.Role of deoxy group on the high concentration of graphene in surfactant/water media[J].RSC advances,2013,3(7):2369-2378.
[28]LOYTA M,KING P J,KHAN U,et al.High-concentration,surfactant-stabilized grapheme dispersions[J].ACS nano,2010,4(6):3155-3162.
[29]SUN Z,MASA J,LIU Z,et al.Highly concentrated aqueous dispersions of graphene exfoliated by sodium taurodeoxycholate:dispersion behavior and potential application as a catalyst support for the oxygen-reduction reaction[J].Chemistry(a european journal),2012,18(22):6972-6978.
[30]PARVIZ D,DAS S,AHMED H S T,et al.Dispersion of non-covalently functionalized graphene with minimal stabilizer[J].ACS nano,2012,6(10):8857-8867.
[31]NARAYAN R,LIM J,JEON T,et al.Perylenetetracarboxylate surfactant assisted liquid phase exfoliation of graphite into grapheme nanosheets with facile redispersibility in aqueous/organic polar solvents[J].Carbon,2017,119:555-568.
[32]YANG H,HERNANDEZ Y,SCHLIERF A,et al.A simple method for graphene production based on exfoliation of graphite in water using 1-pyrenesulfonic acid sodium salt[J].Carbon,2013,53(3):357-365.
[33]NOTLEY S M,Highly concentrated aqueous suspensions of graphene through ultrasonic exfoliation with continuous surfactant addition[J].Langmuir,2012,28(40):14110-14113.
[34]BOURLINOS A B,GEORGAKILAS V,ZBORIL R,et al.Aqueous-phase exfoliation of graphite in the presence of polyvinylpyrrolidone for the production of water-soluble graphenes[J].Solid state communications,2009,149(47-48):2172-2176.
[35]杨青.石墨烯分散体系的制备及其性能研究[D].上海:华东理工大学,2017.YANG Qing.Preparation and performance of grapheme dispersions[D].Shanghai:East China University of Science and Technology,2017.
[36]GUARDIA L,FERNáNDEZ-MERINO M J,PAREDESJ I,et al.High-throughput production of pristine graphene in an aqueous dispersion assisted by non-ionic surfactants[J].Carbon,2011,49(5):1653-1662.
[37]CUI J,SONG Z,XIN L,et al.Exfoliation of graphite to few-layer graphene in aqueous media with vinylimidazole-based polymer as high-performance stabilizer[J].Carbon,2016,99:249-260.
[38]KABE R,FENG X L,ADACHI C,et al.Exfoliation of graphite into graphene in polar solvents mediated by amphiphilic hexa-peri-hexabenzocoronene[J].Chemistry a sian journal,2014,9(11):3125-3129.
[39]WAJID A S,DAS S,IRIN F,et al.Polymer-stabilized graphene dispersions at high concentrations in organic solvents for composite production[J].Carbon,2012,50(2):526-534.
[40]BANG G S,SO H M,LEE M J,et al.Preparation of graphene with few defects using expanded graphite and rose bengal[J].Journal of materials chemistry,2012,22(11):4806-4810.
[41]XU L X,MCGRAW J W,FAN G,et al.Production of high-concentration graphene dispersions in low-boilingpoint organic solvents by liquid-phase noncovalent exfoliation of graphite with a hyperbranched polyethylene and formation of graphene/ethylene copolymer composites[J].The journal of physical chemistry C,2013,117(20):10730-10742.
[42]XIAO W J,SUN Z Y,CHEN S,et al.Ionic liquid-stabilized graphene and its use in immobilizing a metal nanocatalyst[J].RSC advances,2012(2):8189-8193.
[43]NUVOLI D,VALENTINI L,ALZARI V.High concentration few-layer graphene sheets obtained by liquid exfoliation of graphite in ionic liquid[J].The journal of material chemistry,2011(21):3428-3431.
[44]KHAN U,O'NEILL A,LOYTA M,et al.High-concentration solvent exfoliation of graphene[J].Small,2010,6(7):864-871.
[45]LIU C Q,HU G X,GAO H Y.Preparation of few-layer and single-layer by exfoliation of expandable graphite in supercritical N,N-dimethylformamide[J].The journal of supercritical fluids,2012,63:99-104.
[46]GAO Y H,SHI W,WANG W C,et al.Ultrasonic-assisted production of graphene with high yield in supercritical CO2 and its high electrical conductivity film[J].Industrial&engineering chemistry research,2014,53:2839-2845.
[47]HERNANDEZ Y,NICOLOSI V,LOTYA M,et al.Highyield production of graphene by liquid-phase exfoliation of graphite[J].Nature nanotechnology,2008,3(9):563-568.
[48]NARAYAN R,KIM S O.Surfactant mediated liquid phase exfoliation of graphene[J].Nano convergence,2015,2(1):20.
[49]洪庭旭.界面活性剂溶液湿润疏水表面之行为[D].台湾:台湾中央大学,1916.HONG Ting-xu.Wetting behavior of surfactant solutions on hydrophobic surface:copper and telfon[D].Taiwan:National Central University,1916.
[50]DU W,JIANG X,ZHU L.From graphite to graphene:direct liquid-phase exfoliation of graphite to produce single-and few-layered pristine graphene[J].Journal of materials chemistry A,2013,36(1):10592-10606.
[51]BEPETE G,ANGLARET E,ORTOLANI L,et al.Surfactant-free single-layer graphene in water[J].Nature chemistry,2017,9(4):347-352.
[52]CHEN J P,SHI W L,DONG F,et al.A binary solvent system for improved liquid phase exfoliation of pristine grapheme materials[J].Carbon,2015,94:405-411.
[53]祁帅,黄国强.超声波辅助二元溶剂剥离制备石墨烯[J].材料导报A,2017,31(5):72-76.QI Shuai,HUANG Guo-qiang.Preparation of graphene by ultrasonic-assisted exfoliation of graphite in binary solvents[J].Materials review A,2017,31(5):72-76.
[54]PERUMAL S,LEE H M,CHEONG I W.Highconcentration graphene dispersion stabilized by block copolymers in ethanol[J].Journal of colloid and interface science,2017,497:359-367.