木塑复合材料主要组分定量分析方法研究进展
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摘要
作为一种绿色环保型复合材料,木塑复合材料(WPC)具有较好的尺寸稳定性及力学性能,在室内装饰、室外园林景观、建筑、汽车内饰及包装运输等领域有着广泛应用。WPC主成分定量分析对于其市场监管、生产过程中的质量控制及消费者合法权益保证至关重要。文中总结WPC的主要组分,系统梳理目前国内外WPC主要组分定量分析方法的研究现状,分析各方法的优势与劣势,并针对今后的研究提出建议,以期为WPC主成分定量分析方法的进一步研究和推广应用提供参考。
As an environmentally friendly material,wood plastic composites( WPC) has the high stability and good machinability,which thus are widely used in interior decoration and exterior applications to landscaping,building and packaging. Quantitative analysis of the main compositions of WPC is important for market supervision,production quality control and the protection of the legitimate rights and interests of consumers. This paper summarized the main compositions of WPC,systematically reviewed the research advances on the national and international quantitative analysis methods for the main WPC composition determination,and analyzed the advantages and disadvantages of the methods. Then,suggestions on the future research were also proposed with the expectation to provide references for further study and application of quantitative composition analysis and determination of WPC.
As an environmentally friendly material,wood plastic composites( WPC) has the high stability and good machinability,which thus are widely used in interior decoration and exterior applications to landscaping,building and packaging. Quantitative analysis of the main compositions of WPC is important for market supervision,production quality control and the protection of the legitimate rights and interests of consumers. This paper summarized the main compositions of WPC,systematically reviewed the research advances on the national and international quantitative analysis methods for the main WPC composition determination,and analyzed the advantages and disadvantages of the methods. Then,suggestions on the future research were also proposed with the expectation to provide references for further study and application of quantitative composition analysis and determination of WPC.
引文
[1]许民,李坚.生物质-塑料复合工艺学[M].北京:科学出版社,2006:2-18.
[2]姜峰,秦特夫.木塑复合材料增韧性能研究[D].北京:中国林业科学研究院,2007:1-10.
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[5]CHEN H C,CHEN T Y,HSU C H.Effects of wood particle size and mixing ratios of HDPE on the properties of the composites[J].Holz als Roh-und Werkstoff,2006,64(3):172-177.
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[7]SOMBATSOMPOP N,CHAOCHANCHAIKUL K,PHROMCHIRASUKC,et al.Effect of wood sawdust content on rheological and structural changes,and thermos-mechanical properties of PVC/sawdust composites[J].Polymer International,2003,52(12):1847-1855.
[8]郭丽华.马来酸酐/硅烷接枝聚丙烯界面相容剂制备及其性能研究[D].哈尔滨:东北林业大学,2011:1-15.
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[10]李自强.木塑复合材料制备及性能研究[D].济南:山东大学,2009:1-10.
[11]KONG Z,ZHANG W Q,HONG X Q.Study on extrusion of poly(vinyi chloride)/wood flour composite[J].Modern Plastics Processing and Applications,2007,19(2):27-31.
[12]LI J,LI B,ZHANG X,et al.The study of flame retardants on thermal degradation and charring process of manchurian ash lignin in the condensed phase[J].Polymer Degradation and Stability,2001,72(3):493-498.
[13]陈文怡,官建国.高分子材料固化过程的热分析研究进展[J].武汉理工大学学报,2002,24(11):22-24.
[14]WINDT M,MEIER D,LEHNEN R.Quantification of polypropylene(PP)in wood plastic composites(WPCs)by analytical pyrolysis(Py)and differential scanning calorimetry(DSC)[J].Holzforschung,2011,65(2):199-207.
[15]王文钊,刘朝.纤维素热重分析及热解燃烧动力学研究[D].重庆:重庆大学,2008:1-12.
[16]张龙,李树刚.基于热重动力学的含硫矿石自然倾向性研究[D].西安:西安科技大学,2008:1-11.
[17]FUAD M Y,ZAINI M J,JAMALUDIN M,et al.Determination of filler content in rice husk ash and wood-based composites by thermogravimetric analysis[J].Journal of Applied Polymer Science,1994,51(11):1875-1882.
[18]RENNECAKR S,ZINK-SHARP A G,WARD T C,et al.Compositional analysis of thermoplastic wood composites by TGA[J].Journal of Applied Polymer Science,2004,93(3):1484-1492.
[19]JESKE H,SCHIRP A,CORNELIUS F.Development of a thermogravi metric analysis(TGA)method for quantitative analysis of wood flour and polypropylene in wood plastic composites(WPC)[J].Thermochimica Acta,2012,543:165-171.
[20]WAMPLER T,ZAWODNY C,MANCINI L,et al.Investigation of monomer ratios in random and block copolymers of ethylene and propylene using pyrolysis-gas chromatography/mass spectrometr[J].Journal of Analytical and Applied Pyrolysis,2003,68:25-36.
[21]芦永军.近红外光谱分析技术及其在人参成份分析中的应用研究[D].北京:中国科学院,2004:1-5.
[22]LOHUMI S.Study on rapid measurement of wood powder concentration of wood-plastic composites using FT-NIR and FT-IR spectroscopy techniques[J].Journal of the Korean Wood Science&Technology,2016,44(6):852-863.
[23]LI G,LAO W,ZOU X,et al.Use of near-infrared spectroscopy for prediction of biomass and polypropylene in wood plastic composites[J].Wood Science&Technology,2016,50(4):705-714.
[24]TUCKER M P,NGUYEN Q A,EDDY F P,et al.Fourier transform infrared quantitative analysis of sugars and lignin in pretreated softwood solid residues[J].Applied Biochemistry and Biotechnology,2001,91(1/2/3/4/5/6/7/8/9):51-61.
[25]TAMAKI Y,MAZZA G.Rapid determination of carbohydrates,ash,and extractives contents of straw using attenuated total reflectance Fourier transform mid-infrared spectroscopy[J].Journal of Agricultural and Food Chemistry,2011,59(12):6346-6352.
[26]RODRIGUES J,FAIX O,PEREIRA H.Determination of lignin content of Eucalyptus globulus wood using FTIR spectroscopy[J].Holzforschung,1998,52(1):46-50.
[27]PANDEY K K,PITMAN A J.Examination of the lignin content in a softwood and a hardwood decayed by a brown-rot fungus with the acetyl bromide method and Fourier transform infrared spectroscopy[J].Journal of Polymer Science Part A:Polymer Chemistry,2004,42(10):2340-2346.
[28]LEE C H,WU T L,CHEN Y L,et al.Characteristics and discrimination of five types of wood-plastic composites by FTIR spectroscopy combined with principal component analysis[J].Holzforschung,2010,64(6):699-704.
[29]劳万里,李改云,周群,等.红外光谱法测定杉木/聚丙烯复合材料中木粉和塑料含量[J].光谱学与光谱分析,2015,35(6):1546-1550.
[30]劳万里,李改云,秦特夫,等.红外光谱结合多元线性回归法快速测定木塑复合材料中木粉含量[J].林产化学与工业,2015,35(3):20-26.
[31]劳万里,何玉婵,李改云,等.红外光谱结合偏最小二乘法定量分析毛竹/聚丙烯复合材料的主成分[J].光谱学与光谱分析,2016,36(1):55-59.
[32]LAO W,LI G,ZHOU Q,et al.Quantitative analysis of biomass in three types of wood-plastic composites by FTIR spectroscopy[J].Bioresources,2014,9(4):6073-6086.
[33]LI G,LAO W,QIN T,et al.Rapid determination of biomass and polypropylene in three types of wood plastic composites(WPCs)using FTIR spectroscopy and partial least squares regression(PLSR)[J].Holzforschung,2015,69(4):399-404.
[2]姜峰,秦特夫.木塑复合材料增韧性能研究[D].北京:中国林业科学研究院,2007:1-10.
[3]RIMDUSIT S,WONGSONGYOT S,JITTAROM S,et al.Effects of gamma irradiation with and without compatibilizer on the mechanical properties of polypropylene/wood flour composites[J].Journal of Polymer Research,2011,18(4):801-809.
[4]STARK N.Influence of moisture absorption on mechanical properties of wood flour-polypropylene composites[J].Journal of Thermoplastic Composite Materials,2001,14(5):421-432.
[5]CHEN H C,CHEN T Y,HSU C H.Effects of wood particle size and mixing ratios of HDPE on the properties of the composites[J].Holz als Roh-und Werkstoff,2006,64(3):172-177.
[6]NAGHIPOUR B.Effect of extreme environmental conditions and fungal expore on the properties of wood-plastic composites[D].Toronto:University of Toronto,1996:6-12.
[7]SOMBATSOMPOP N,CHAOCHANCHAIKUL K,PHROMCHIRASUKC,et al.Effect of wood sawdust content on rheological and structural changes,and thermos-mechanical properties of PVC/sawdust composites[J].Polymer International,2003,52(12):1847-1855.
[8]郭丽华.马来酸酐/硅烷接枝聚丙烯界面相容剂制备及其性能研究[D].哈尔滨:东北林业大学,2011:1-15.
[9]JIN S.Improving the durability and mechanical properties of woodplastic composites through coextrusion[D].East Lansing:Michigan State University,2010:1-20.
[10]李自强.木塑复合材料制备及性能研究[D].济南:山东大学,2009:1-10.
[11]KONG Z,ZHANG W Q,HONG X Q.Study on extrusion of poly(vinyi chloride)/wood flour composite[J].Modern Plastics Processing and Applications,2007,19(2):27-31.
[12]LI J,LI B,ZHANG X,et al.The study of flame retardants on thermal degradation and charring process of manchurian ash lignin in the condensed phase[J].Polymer Degradation and Stability,2001,72(3):493-498.
[13]陈文怡,官建国.高分子材料固化过程的热分析研究进展[J].武汉理工大学学报,2002,24(11):22-24.
[14]WINDT M,MEIER D,LEHNEN R.Quantification of polypropylene(PP)in wood plastic composites(WPCs)by analytical pyrolysis(Py)and differential scanning calorimetry(DSC)[J].Holzforschung,2011,65(2):199-207.
[15]王文钊,刘朝.纤维素热重分析及热解燃烧动力学研究[D].重庆:重庆大学,2008:1-12.
[16]张龙,李树刚.基于热重动力学的含硫矿石自然倾向性研究[D].西安:西安科技大学,2008:1-11.
[17]FUAD M Y,ZAINI M J,JAMALUDIN M,et al.Determination of filler content in rice husk ash and wood-based composites by thermogravimetric analysis[J].Journal of Applied Polymer Science,1994,51(11):1875-1882.
[18]RENNECAKR S,ZINK-SHARP A G,WARD T C,et al.Compositional analysis of thermoplastic wood composites by TGA[J].Journal of Applied Polymer Science,2004,93(3):1484-1492.
[19]JESKE H,SCHIRP A,CORNELIUS F.Development of a thermogravi metric analysis(TGA)method for quantitative analysis of wood flour and polypropylene in wood plastic composites(WPC)[J].Thermochimica Acta,2012,543:165-171.
[20]WAMPLER T,ZAWODNY C,MANCINI L,et al.Investigation of monomer ratios in random and block copolymers of ethylene and propylene using pyrolysis-gas chromatography/mass spectrometr[J].Journal of Analytical and Applied Pyrolysis,2003,68:25-36.
[21]芦永军.近红外光谱分析技术及其在人参成份分析中的应用研究[D].北京:中国科学院,2004:1-5.
[22]LOHUMI S.Study on rapid measurement of wood powder concentration of wood-plastic composites using FT-NIR and FT-IR spectroscopy techniques[J].Journal of the Korean Wood Science&Technology,2016,44(6):852-863.
[23]LI G,LAO W,ZOU X,et al.Use of near-infrared spectroscopy for prediction of biomass and polypropylene in wood plastic composites[J].Wood Science&Technology,2016,50(4):705-714.
[24]TUCKER M P,NGUYEN Q A,EDDY F P,et al.Fourier transform infrared quantitative analysis of sugars and lignin in pretreated softwood solid residues[J].Applied Biochemistry and Biotechnology,2001,91(1/2/3/4/5/6/7/8/9):51-61.
[25]TAMAKI Y,MAZZA G.Rapid determination of carbohydrates,ash,and extractives contents of straw using attenuated total reflectance Fourier transform mid-infrared spectroscopy[J].Journal of Agricultural and Food Chemistry,2011,59(12):6346-6352.
[26]RODRIGUES J,FAIX O,PEREIRA H.Determination of lignin content of Eucalyptus globulus wood using FTIR spectroscopy[J].Holzforschung,1998,52(1):46-50.
[27]PANDEY K K,PITMAN A J.Examination of the lignin content in a softwood and a hardwood decayed by a brown-rot fungus with the acetyl bromide method and Fourier transform infrared spectroscopy[J].Journal of Polymer Science Part A:Polymer Chemistry,2004,42(10):2340-2346.
[28]LEE C H,WU T L,CHEN Y L,et al.Characteristics and discrimination of five types of wood-plastic composites by FTIR spectroscopy combined with principal component analysis[J].Holzforschung,2010,64(6):699-704.
[29]劳万里,李改云,周群,等.红外光谱法测定杉木/聚丙烯复合材料中木粉和塑料含量[J].光谱学与光谱分析,2015,35(6):1546-1550.
[30]劳万里,李改云,秦特夫,等.红外光谱结合多元线性回归法快速测定木塑复合材料中木粉含量[J].林产化学与工业,2015,35(3):20-26.
[31]劳万里,何玉婵,李改云,等.红外光谱结合偏最小二乘法定量分析毛竹/聚丙烯复合材料的主成分[J].光谱学与光谱分析,2016,36(1):55-59.
[32]LAO W,LI G,ZHOU Q,et al.Quantitative analysis of biomass in three types of wood-plastic composites by FTIR spectroscopy[J].Bioresources,2014,9(4):6073-6086.
[33]LI G,LAO W,QIN T,et al.Rapid determination of biomass and polypropylene in three types of wood plastic composites(WPCs)using FTIR spectroscopy and partial least squares regression(PLSR)[J].Holzforschung,2015,69(4):399-404.