材料表面膨胀型涂层应用进展
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摘要
阻燃涂层作为一种方便、经济和有效的手段被广泛应用于各种基材(如金属、聚合物、纺织品和木材)的表面上,赋予基材阻燃防火性能。层层自组装技术是一种新兴技术,可用于赋予基材不同的特性。相比于传统阻燃工艺,层层自组装技术具有功能可调、制备工艺条件温和、可重复使用、环境友好等优点。目前,利用层层自组装技术可在织物、薄膜和泡沫上沉积新型膨胀型涂层。
Flame retardant coatings are widely used as a convenient,economical and effective means to impart the fire resistance to metals,polymers,textiles and wood.Layer-by-layer(LbL)self-assembly technology is an emerging technology for imparting different characteristics to substrates.Compared with the traditional flame retardant technology,the LbL self-assembly technology has such advantages as adjustable function,mild conditions,recycling and environmental friendliness.The current intumescent coatings for metals,wood and plastics were described,and introduced the LbL assembly techniques used to deposit new intumescent coatings on fabrics,films and foams.
Flame retardant coatings are widely used as a convenient,economical and effective means to impart the fire resistance to metals,polymers,textiles and wood.Layer-by-layer(LbL)self-assembly technology is an emerging technology for imparting different characteristics to substrates.Compared with the traditional flame retardant technology,the LbL self-assembly technology has such advantages as adjustable function,mild conditions,recycling and environmental friendliness.The current intumescent coatings for metals,wood and plastics were described,and introduced the LbL assembly techniques used to deposit new intumescent coatings on fabrics,films and foams.
引文
[1]徐晓楠.防火涂料[M].北京:化学工业出版社材料科学与工程出版中心,2004.
[2]翟丽娜,李俊.服装热防护性能测评技术的发展过程及现状[J].纺织学报,2015,36(7):162-168.
[3]覃文清.材料表面涂层防火阻燃技术[M].北京:化学工业出版社,2004.
[4]Weil E D.Fire-protective and flame-retardant coatings-a stateof-the-art review[J].Journal of Fire Sciences,2011,29(3):259-296.
[5]Han Z,Fina A,Malucelli G,et al.Testing fire protective properties of intumescent coatings by in-line,temperature measurements on a cone calorimeter[J].Progress in Organic Coatings,2010,69(4):475-480.
[6]Alongi J,Han Z,Bourbigot S.Intumescence:tradition versus novelty.a comprehensive review[J].Progress in Polymer Science,2015,51:28-73.
[7]Dai X H,Wang Y C,Bailey C G.Effects of partial fire protection on temperature developments in steel joints protected by intumescent coating[J].Fire Safety Journal,2009,44(3):376-386.
[8]N?rgaard K P,Dam-Johansen K,CatalàP,et al.Investigation of char strength and expansion properties of an intumescent coating exposed to rapid heating rates[J].Progress in Organic Coatings,2013,76(12):1851-1857.
[9]Zhang Y,Wang Y C,Bailey C G,et al.Global modelling of fire protection performance of intumescent coating under different cone calorimeter heating conditions[J].Fire Safety Journal,2012,50(50):51-62.
[10]Staggs J E J,Crewe R J,Butler R.A theoretical and experimental investigation of intumescent behaviour in protective coatings for structural steel[J].Chemical Engineering Science,2012,71(13):239-251.
[11]Jimenez M,Duquesne S,Bourbigot S.Kinetic analysis of the thermal degradation of an epoxy-based intumescent coating[J].Polymer Degradation &Stability,2009,94(3):404-409.
[12]Duquesne S,Magnet S,Jama C,et al.Intumescent paints:fire protective coatings for metallic substrates[J].Surface &Coatings Technology,2004,s180-181(3):302-307.
[13]Gérard C,Fontaine G,Bellayer S,et al.Reaction to fire of an intumescent epoxy resin:protection mechanisms and synergy[J].Polymer Degradation &Stability,2012,97(8):1366-1386.
[14]Jimenez M,Bellayer S,Revel B,et al.Comprehensive study of the influence of different aging scenarios on the fire protective behavior of an epoxy based intumescent coating[J].Industrial&Engineering Chemistry Research,2013,52(2):729-743.
[15]Dong Y,Wang G,Yang J.Influences of silicone emulsion on fire protection of waterborne intumescent fire-resistive coating[J].Journal of Coatings Technology &Research,2014,11(2):231-237.
[16]Ming C Y,Sulong N H R.Fire-resistive performance of intumescent flame-retardant coatings for steel[J].Materials &Design,2012,34:719-724.
[17]刘学军,付若愚,郭奋,等.膨胀型钢结构防火涂料膨胀炭质层的隔热作用[J].北京化工大学学报(自然科学版),2005,32(1):16-20.
[18]Arksey H,Glendinning C.Nanostructured protective coating systems,fireproof and environmentally friendly,suitable for the protection of metallic substrates[J].Industrial &Engineering Chemistry Research,2010,49(6):2740-2746.
[19]刘国钦,邹敏,王军,等.纳米材料改性新型钢结构防火涂料的研究[J].成都理工大学学报(自科版),2003,30(4):413-416.
[20]Wang Z,Han E,Ke W.Fire-resistant effect of nanoclay on intumescent nanocomposite coatings[J].Journal of Applied Polymer Science,2007,103(3):1681-1689.
[21]Maraveas C,Miamis K,Matthaiou C E.Performance of timber connections exposed to fire:a review[J].Fire Technology,2015,51(6):1401-1432.
[22]Lowden L A,Hull T R.Flammability behaviour of wood and a review of the methods for its reduction[J].Fire Science Reviews,2013,2(1):4.
[23]Chuang C S,Yang T H,Tsai K C,et al.Fire retardancy and CO/CO2emission of intumescent coatings on thin plywood panel with waterborne vinyl acetate-acrylic resin[J].Wood Science &Technology,2013,47(2):353-367.
[24]Canosa G,Alfieri P V,Giudice C A.Hybrid intumescent coatings for wood protection against fire action[J].Industrial &Engineering Chemistry Research,2011,50(21):11897-11905.
[25]姜定,杨成志,田瑶珠,等.膨胀型阻燃涂料对木材的阻燃性能[J].高分子材料科学与工程,2016,32(12):49-54.
[26]Hassan M A,Kozlowski R,Obidzinski B.New fire-protective intumescent coatings for wood[J].Journal of Applied Polymer Science,2008,110:83-90.
[27]廖阳飞,张旭东.塑料涂料研究进展[J].上海涂料,2008,46(8):14-18.
[28]高原,邢安,殷军港,等.高分子基材料表面改性研究进展[J].高分子材料科学与工程,2012,28(6):172-175.
[29]刘登良.塑料橡胶涂料与涂装技术[M].北京:化学工业出版社,2001.
[30]彭博,高敬民,李鸿岩,等.高分子基材表面用阻燃涂料研究进展[J].现代涂料与涂装,2013,16(11):20-26.
[31]Jimenez M,Duquesne S,Bourbigot S.Fire protection of polypropylene and polycarbonate by intumescent coatings(pages130-135)[C]//Wseas International Conference on Materials Science.World Scientific and Engineering Academy and Society(WSEAS),2008:82-85.
[32]Duquesne S,Jimenez M,Bourbigot S.Aging of the flame-retardant properties of polycarbonate and polypropylene protected by an intumescent coating[J].Journal of Applied Polymer Science,2014,131(3):712-717.
[33]Iler R K.Multilayers of colloidal particles[J].Journal of Colloid &Interface Science,1966,21(6):569-594.
[34]Decher G,Hong J D,Schmitt J,et al.Buildup of ultrathin multilayer films by a self-assembly process:Ⅲ.Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces[J].Thin Solid Films,1992,210-211(2):831-835.
[35]Rydzek G,Schaaf P,Voegel J C,et al.Strategies for covalently reticulated polymer multilayers[J].Soft Matter,2012,8(38):9738-9755.
[36]任元林,张悦,曾倩,等.织物阻燃涂层新工艺的研究进展[J].纺织学报,2017,38(9).
[37]Srikulkit K,Iamsamai C,Dubas S T.Development of flame retardant polyphosphoric acid coating based on the polyelectrolyte multilayers technique[J].Journal of Metals,Materials and Minerals,2017,16(2).
[38]Huang G,Liang H,Wang X,et al.Poly(acrylic acid)/clay thin films assembled by layer-by-layer deposition for improving the flame retardancy properties of cotton[J].Industrial &Engineering Chemistry Research,2012,51(38):12299-12309.
[39]Huang G,Yang J,Gao J,et al.Thin films of intumescent flame retardant-polyacrylamide and exfoliated graphene oxide fabricated via layer-by-layer assembly for improving flame retardant properties of cotton fabric[J].Industrial &Engineering Chemistry Research,2012,51(38):12355-12366.
[40]Li Y,Sarah M,Morgan A B,et al.Intumescent all-polymer multilayer nanocoating capable of extinguishing flame on fabric[J].Advanced Materials,2011,23(34):3926.
[41]Apaydin K,Laachachi A,Ball V,et al.Intumescent coating of(polyallylamine-polyphosphates)deposited on polyamide fabrics via layer-by-layer technique[J].Polymer Degradation &Stability,2014,106(8):158-164.
[42]Apaydin K,Laachachi A,Ball V,et al.Polyallylamine-montmorillonite as super flame retardant coating assemblies bylayer-by layer deposition on polyamide[J].Polymer Degradation&Stability,2013,98(2):627-634.
[43]Laachachi A,Ball V,Apaydin K,et al.Diffusion of polyphosphates into(poly(allylamine)-montmorillonite)multilayer films:flame retardant-intumescent films with improved oxygen barrier[J].Langmuir,2011,27(22):13879-87.
[44]杨君驰,黄鉴前,陈力,等.三聚氰胺泡沫层层组装阻燃改性研究[C]//全国高分子学术论文报告会,2013.
[45]Laufer G,Kirkland C,Cain A A,et al.Clay-chitosan nanobrick walls:completely renewable gas barrier and flame-retardant nanocoatings[J].ACS Applied Materials &Interfaces,2012,4(3):1643.
[46]潘海峰.棉织物和软质聚氨酯泡沫的层层自组装阻燃涂层的设计及其性能研究[D].合肥:中国科学技术大学,2015.
[2]翟丽娜,李俊.服装热防护性能测评技术的发展过程及现状[J].纺织学报,2015,36(7):162-168.
[3]覃文清.材料表面涂层防火阻燃技术[M].北京:化学工业出版社,2004.
[4]Weil E D.Fire-protective and flame-retardant coatings-a stateof-the-art review[J].Journal of Fire Sciences,2011,29(3):259-296.
[5]Han Z,Fina A,Malucelli G,et al.Testing fire protective properties of intumescent coatings by in-line,temperature measurements on a cone calorimeter[J].Progress in Organic Coatings,2010,69(4):475-480.
[6]Alongi J,Han Z,Bourbigot S.Intumescence:tradition versus novelty.a comprehensive review[J].Progress in Polymer Science,2015,51:28-73.
[7]Dai X H,Wang Y C,Bailey C G.Effects of partial fire protection on temperature developments in steel joints protected by intumescent coating[J].Fire Safety Journal,2009,44(3):376-386.
[8]N?rgaard K P,Dam-Johansen K,CatalàP,et al.Investigation of char strength and expansion properties of an intumescent coating exposed to rapid heating rates[J].Progress in Organic Coatings,2013,76(12):1851-1857.
[9]Zhang Y,Wang Y C,Bailey C G,et al.Global modelling of fire protection performance of intumescent coating under different cone calorimeter heating conditions[J].Fire Safety Journal,2012,50(50):51-62.
[10]Staggs J E J,Crewe R J,Butler R.A theoretical and experimental investigation of intumescent behaviour in protective coatings for structural steel[J].Chemical Engineering Science,2012,71(13):239-251.
[11]Jimenez M,Duquesne S,Bourbigot S.Kinetic analysis of the thermal degradation of an epoxy-based intumescent coating[J].Polymer Degradation &Stability,2009,94(3):404-409.
[12]Duquesne S,Magnet S,Jama C,et al.Intumescent paints:fire protective coatings for metallic substrates[J].Surface &Coatings Technology,2004,s180-181(3):302-307.
[13]Gérard C,Fontaine G,Bellayer S,et al.Reaction to fire of an intumescent epoxy resin:protection mechanisms and synergy[J].Polymer Degradation &Stability,2012,97(8):1366-1386.
[14]Jimenez M,Bellayer S,Revel B,et al.Comprehensive study of the influence of different aging scenarios on the fire protective behavior of an epoxy based intumescent coating[J].Industrial&Engineering Chemistry Research,2013,52(2):729-743.
[15]Dong Y,Wang G,Yang J.Influences of silicone emulsion on fire protection of waterborne intumescent fire-resistive coating[J].Journal of Coatings Technology &Research,2014,11(2):231-237.
[16]Ming C Y,Sulong N H R.Fire-resistive performance of intumescent flame-retardant coatings for steel[J].Materials &Design,2012,34:719-724.
[17]刘学军,付若愚,郭奋,等.膨胀型钢结构防火涂料膨胀炭质层的隔热作用[J].北京化工大学学报(自然科学版),2005,32(1):16-20.
[18]Arksey H,Glendinning C.Nanostructured protective coating systems,fireproof and environmentally friendly,suitable for the protection of metallic substrates[J].Industrial &Engineering Chemistry Research,2010,49(6):2740-2746.
[19]刘国钦,邹敏,王军,等.纳米材料改性新型钢结构防火涂料的研究[J].成都理工大学学报(自科版),2003,30(4):413-416.
[20]Wang Z,Han E,Ke W.Fire-resistant effect of nanoclay on intumescent nanocomposite coatings[J].Journal of Applied Polymer Science,2007,103(3):1681-1689.
[21]Maraveas C,Miamis K,Matthaiou C E.Performance of timber connections exposed to fire:a review[J].Fire Technology,2015,51(6):1401-1432.
[22]Lowden L A,Hull T R.Flammability behaviour of wood and a review of the methods for its reduction[J].Fire Science Reviews,2013,2(1):4.
[23]Chuang C S,Yang T H,Tsai K C,et al.Fire retardancy and CO/CO2emission of intumescent coatings on thin plywood panel with waterborne vinyl acetate-acrylic resin[J].Wood Science &Technology,2013,47(2):353-367.
[24]Canosa G,Alfieri P V,Giudice C A.Hybrid intumescent coatings for wood protection against fire action[J].Industrial &Engineering Chemistry Research,2011,50(21):11897-11905.
[25]姜定,杨成志,田瑶珠,等.膨胀型阻燃涂料对木材的阻燃性能[J].高分子材料科学与工程,2016,32(12):49-54.
[26]Hassan M A,Kozlowski R,Obidzinski B.New fire-protective intumescent coatings for wood[J].Journal of Applied Polymer Science,2008,110:83-90.
[27]廖阳飞,张旭东.塑料涂料研究进展[J].上海涂料,2008,46(8):14-18.
[28]高原,邢安,殷军港,等.高分子基材料表面改性研究进展[J].高分子材料科学与工程,2012,28(6):172-175.
[29]刘登良.塑料橡胶涂料与涂装技术[M].北京:化学工业出版社,2001.
[30]彭博,高敬民,李鸿岩,等.高分子基材表面用阻燃涂料研究进展[J].现代涂料与涂装,2013,16(11):20-26.
[31]Jimenez M,Duquesne S,Bourbigot S.Fire protection of polypropylene and polycarbonate by intumescent coatings(pages130-135)[C]//Wseas International Conference on Materials Science.World Scientific and Engineering Academy and Society(WSEAS),2008:82-85.
[32]Duquesne S,Jimenez M,Bourbigot S.Aging of the flame-retardant properties of polycarbonate and polypropylene protected by an intumescent coating[J].Journal of Applied Polymer Science,2014,131(3):712-717.
[33]Iler R K.Multilayers of colloidal particles[J].Journal of Colloid &Interface Science,1966,21(6):569-594.
[34]Decher G,Hong J D,Schmitt J,et al.Buildup of ultrathin multilayer films by a self-assembly process:Ⅲ.Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces[J].Thin Solid Films,1992,210-211(2):831-835.
[35]Rydzek G,Schaaf P,Voegel J C,et al.Strategies for covalently reticulated polymer multilayers[J].Soft Matter,2012,8(38):9738-9755.
[36]任元林,张悦,曾倩,等.织物阻燃涂层新工艺的研究进展[J].纺织学报,2017,38(9).
[37]Srikulkit K,Iamsamai C,Dubas S T.Development of flame retardant polyphosphoric acid coating based on the polyelectrolyte multilayers technique[J].Journal of Metals,Materials and Minerals,2017,16(2).
[38]Huang G,Liang H,Wang X,et al.Poly(acrylic acid)/clay thin films assembled by layer-by-layer deposition for improving the flame retardancy properties of cotton[J].Industrial &Engineering Chemistry Research,2012,51(38):12299-12309.
[39]Huang G,Yang J,Gao J,et al.Thin films of intumescent flame retardant-polyacrylamide and exfoliated graphene oxide fabricated via layer-by-layer assembly for improving flame retardant properties of cotton fabric[J].Industrial &Engineering Chemistry Research,2012,51(38):12355-12366.
[40]Li Y,Sarah M,Morgan A B,et al.Intumescent all-polymer multilayer nanocoating capable of extinguishing flame on fabric[J].Advanced Materials,2011,23(34):3926.
[41]Apaydin K,Laachachi A,Ball V,et al.Intumescent coating of(polyallylamine-polyphosphates)deposited on polyamide fabrics via layer-by-layer technique[J].Polymer Degradation &Stability,2014,106(8):158-164.
[42]Apaydin K,Laachachi A,Ball V,et al.Polyallylamine-montmorillonite as super flame retardant coating assemblies bylayer-by layer deposition on polyamide[J].Polymer Degradation&Stability,2013,98(2):627-634.
[43]Laachachi A,Ball V,Apaydin K,et al.Diffusion of polyphosphates into(poly(allylamine)-montmorillonite)multilayer films:flame retardant-intumescent films with improved oxygen barrier[J].Langmuir,2011,27(22):13879-87.
[44]杨君驰,黄鉴前,陈力,等.三聚氰胺泡沫层层组装阻燃改性研究[C]//全国高分子学术论文报告会,2013.
[45]Laufer G,Kirkland C,Cain A A,et al.Clay-chitosan nanobrick walls:completely renewable gas barrier and flame-retardant nanocoatings[J].ACS Applied Materials &Interfaces,2012,4(3):1643.
[46]潘海峰.棉织物和软质聚氨酯泡沫的层层自组装阻燃涂层的设计及其性能研究[D].合肥:中国科学技术大学,2015.