钠离子电池硫化物负极材料的研究进展
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摘要
本文回顾了一些金属硫化物在钠离子电池中的应用,钠与锂同族,钠离子电池有望和锂离子电池一样,成为一种极具发展前景的储能装置,所以其电极材料是当下研究的热点。重点介绍了这些材料目前面临的问题,钠离子较大的半径使其在电极材料中存在脱嵌困难、体积膨胀等问题,鉴于层状金属硫化物拥有良好的钠嵌入平台,因而受到研究人员的广泛关注。综述了二硫化钼、二硫化钨、二硫化锡、二硫化钒、二硫化钛几种层状过渡金属二硫化物和硫化镍、硫化锌、硫化铜、硫化亚铁几种非二硫化物负极材料在钠离子电池中的电化学性能,包括了容量和循环性能等。分析了这些材料目前所面临的主要问题是体积膨胀、钠离子扩散缓慢、充放电效率低、多硫化物溶解-穿梭等问题。指出缓解硫化物体积膨胀问题的方法有与碳复合、材料纳米化、控制形貌等,对于层状过渡金属二硫化物还可以通过扩大层间距、调节截止电压等方式提高其电化学性能。最后对过渡金属硫化物负极材料的研究前景进行了展望。
The application of metallic sulfide in sodium-ion battery is reviewed. Sodium and lithium are of the same group, and sodium ion battery is expected to be a promising energy storage device like lithium-ion battery. Therefore, its electrode materials is the current research hotspot. The current problems of these materials are introduced. The large radius of sodium ions leads to difficult intercalation/deintercalation of Na+ for in the electrode materials, and volume expansion etc. In view of good sodium-intercalation platforms of layered metal sulfides, they have attracted extensive attention from researchers. Summarized the electrochemical properties of the molybdenum disulfide, tungsten disulfide, tin disulfide,vanadium disulfide, titanium disulfide several layered transition metal disulfide and nickel sulfide, zinc sulfide, copper sulfide, several kinds of non-disulfide anode materials in sodium-ion batteries, including the capacity and cycle performance etc, Volume expansion、slow diffusion of Na~+、low efficiency of charge and discharge、polysulfide dissolving-shuttling of the main problems faced by these materials at present are analyzed. It is pointed out that the methods to alleviate the volume expansion of sulfides are carbon composite, nano-materials, morphology control etc. For l①aye red transition metal disulfides. the electr ochemical performance can be improved by enlarging theinterlayer spacing and adjusting the cut-off voltage. Finally, the research prospect of transition metal sulfide anode materials is viewed.
The application of metallic sulfide in sodium-ion battery is reviewed. Sodium and lithium are of the same group, and sodium ion battery is expected to be a promising energy storage device like lithium-ion battery. Therefore, its electrode materials is the current research hotspot. The current problems of these materials are introduced. The large radius of sodium ions leads to difficult intercalation/deintercalation of Na+ for in the electrode materials, and volume expansion etc. In view of good sodium-intercalation platforms of layered metal sulfides, they have attracted extensive attention from researchers. Summarized the electrochemical properties of the molybdenum disulfide, tungsten disulfide, tin disulfide,vanadium disulfide, titanium disulfide several layered transition metal disulfide and nickel sulfide, zinc sulfide, copper sulfide, several kinds of non-disulfide anode materials in sodium-ion batteries, including the capacity and cycle performance etc, Volume expansion、slow diffusion of Na~+、low efficiency of charge and discharge、polysulfide dissolving-shuttling of the main problems faced by these materials at present are analyzed. It is pointed out that the methods to alleviate the volume expansion of sulfides are carbon composite, nano-materials, morphology control etc. For l①aye red transition metal disulfides. the electr ochemical performance can be improved by enlarging theinterlayer spacing and adjusting the cut-off voltage. Finally, the research prospect of transition metal sulfide anode materials is viewed.
引文
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[24]NEWMAN G H,KLEMANN L P.Ambient temperature cycling of an Na-TiS2 cell[J].J.Electrochem.Soc.,1980,127:2097-2099.
[25]苏玉平.二维层状过渡金属硫族化合物的结构设计及其储锂/钠性能研究[D].苏州:苏州大学,2018.SU Y P.2D layered transition metal dichalcogenides:Synthesis and characterization and their application in lithium/sodium ion batteries[D].Suzhou:Soochow University,2018.
[26]TAO Hongwei,ZHOU Min,WANG Ruxing,et al.TiS2 as an advanced conversion electrode for sodium-ion batterieswith ultra-high capacity and long-cycle life[J].Adv.Sci.,2018,1801021.
[27]KULLERUD G,YUND R A.The Ni-S system and related minerals[J].Journal of Petrology,1962,3(1):126-175.
[28]CHEN Q,CHEN W,YE J,et al.1-Cysteine-assisted hydrothermal synthesis of nickel disulfide/graphene composite with enhanced electrochemical performance for reversible lithium storage[J].Journal of Power Sources,2015,294:51-58.
[29]RYU H S,KIM J S,PARK J,et al.Degradation mechanism of room temperature Na/Ni3S2 cells using Ni3S2 electrodes prepared by mechanical alloying[J].Journal of Power Sources,2013,244:764-770.
[30]GO D Y,PARK J,NOH P J,et al.Electrochemical properties of monolithic nickel sulfide electrodes for use in sodium batteries[J].Materials Research Bulletin,2014,58:190-194.
[31]秦伟.金属硫化物-石墨烯复合物的微波法制备及其在钠离子电池负极的应用[D].上海:华东师范大学,2016.QIN W.The microwave-assisted synthesis of metal sulfide-graphene composite for the anode of sodium-ion batteries[D].Shanghai:East China Normal University,2016.
[32]HOU B H,WANG Y Y,GUO J Z,et al.Pseudocapacitance-boosted ultrafast Na storage in a pie-like FeS@C nanohybrid as an advanced anode material for sodium-ion full batteries[J].Nanoscale,2018,10(19):9218-9225.
[2]KIM S W,SEOD H,MA X,et al.Electrode materials for rechargeable sodium-ion batteries:Pot-entail alternatives to current lithium ion batteries[J].Advanced Energy Materials,2012,2:710-721.
[3]WANG L P,YU L,WANG X,et al.Recent developments in electrode materials for sodium-ion batteries[J].Journal of Materials Chemistry A,2015,3:9353-9378.
[4]KIM S W,SEO D H,MA X,et al.Electrode materials for rechargeable sodium-ion batteries:Potential altern atives to current lithium-ionbatteries[J].Advanced Energy Materials,2012,2(7):710-721.
[5]ARMAND M B.Materials for advanced batteries:Intercalation electrodes[M].New York:Plenum Press,1980:145-161.
[6]DU Y,ZHU X,ZHOU X,et al.Co3S4 porous nanosheets embedded in graphene sheets as high-performance anode materials for lithium and sodium storage[J].Journal of Materials Chemistry A,2015,3:6787-6791.
[7]ZHU Y,NIE P,SHEN L,et al.High rate capability and superior cycle stability of a flower-like Sb2S3 anode for high-capacity sodium ion batteries[J].Nanoscale,2015,7:3309-3315.
[8]KANG Wenpei,WANG Yuyu,XU Jun.Recent progress in layered metal dichalcogenide nanostructures as electrodes for high-performance sodium-ion batteries[J].Journal of Materials Chemistry A,2017,5:7667-7690.
[9]XIAO Y,LEE S H,SUN Y K.The application of metal sulfides in sodium ion batteries[J].Adv.Energy Mater.,2017,7:1601329-1601349.
[10]TENG Y,ZHAO H,LI Z,et al.MoS2 nanosheets vertically grown on graphene sheets for lithium-batteris[J].ACS Nano,2016,10(9):8526-8535.
[11]SHI Zhengtian,KANG Wenpei,XU Jun,et al.In situ carbon-doped Mo(Se0.85S0.15)2 hierarchical nanotubes as stable anodes for high-performance sodium-ion batteries[J].Small,2015,11(42):5667-5674.
[12]XIE Xiuqiang,MAKARYAN Taron,ZHAO Mengqiang,et al.MoS2nanosheets vertically aligned on carbon paper:A freestanding electrode for highly reversible sodium-ion batteries[J].Advanced Engery Materials,2016,6(5):doi:10.1002/aenm.201502161.
[13]CHOI S H,KO Y N,LEE J K,et al.3D MoS2-graphene microspheres consisting of multiple nanospheres with superior sodium ion storage properties[J].Advanced Functional Materials,2015,25(12):1780-1788.
[14]ARUNVINAY P,FRANK D,JODIE M,et al.WS2 2D nanosheets in3D nanoflowers[J].Chemical Communication,2014,50:12360-12362.
[15]CAO S,LIU T,HUSSAIN S,et al.Hydrothermal synthesis of variety low dimensional WS2 nanostructures[J].Materials Letters,2014,129:205-208.
[16]SEUNG H C,YUN C K.Sodium ion storage properties of WS2-decorated three-dimensional reduced graphene oxide microspheres[J].Nanoscale,2015,7:3965-3970.
[17]SU Dawei,DOU Shixue,WANG Guoxiu.WS2@graphene nanocomposites as anode materials for Na ion batteries with enhanced electrochemical performances[J].Chemical Communication,2014,50:4192-4195.
[18]田丽媛,鞠小霞,向枫,等.钠离子电池金属化合物负极材料的研究进展[J].储能科学与技术,2018,7(6):1211-1216.TIAN Liyuan,JU Xiaoxia,XIANG Feng,et al.Recent research progress of metal compounds as anode materials for sodium-ion batteries[J].Energy Storage Science and Technology,2018,7(6):1211-1216.
[19]QU B,MA C,JI G,et al.Layered SnS2-reduced graphene oxide composite:A high-capacity,high-rate,and long-cycle life sodium-ion battery anode material[J].Advanced Materials,2014,26(23):3854-3859.
[20]FENG J,SUN X,WU C,et al.Metallic few-layered VS2 ultrathin nanosheets:High two-dimensional conductivity for in-piane supercapacitors[J].Journal of the American Chemical Society,2011,133(44):17832-17838.
[21]HE P,YAN M,ZHANG G,et al.Layered VS2 nanosheet-based aqueous Zn ion battery cathode[J].Adv.Energy Mater.,2017,7:doi:10.1002/aenm.201601920.
[22]LIAO J Y,MANTHIRAM A.High-performance Na2Ti2O5 nanowire arrays coated with VS2 nanosheets for sodium-ion storage[J].Nano Energy,2015,18:20-27.
[23]WINN D A,SHEMILT J M,STEELE B C H.Titanium disulphide:Asolid solution electrode for sodium and lithium[J].Mater.Res.Bull.,1976,11:559-566.
[24]NEWMAN G H,KLEMANN L P.Ambient temperature cycling of an Na-TiS2 cell[J].J.Electrochem.Soc.,1980,127:2097-2099.
[25]苏玉平.二维层状过渡金属硫族化合物的结构设计及其储锂/钠性能研究[D].苏州:苏州大学,2018.SU Y P.2D layered transition metal dichalcogenides:Synthesis and characterization and their application in lithium/sodium ion batteries[D].Suzhou:Soochow University,2018.
[26]TAO Hongwei,ZHOU Min,WANG Ruxing,et al.TiS2 as an advanced conversion electrode for sodium-ion batterieswith ultra-high capacity and long-cycle life[J].Adv.Sci.,2018,1801021.
[27]KULLERUD G,YUND R A.The Ni-S system and related minerals[J].Journal of Petrology,1962,3(1):126-175.
[28]CHEN Q,CHEN W,YE J,et al.1-Cysteine-assisted hydrothermal synthesis of nickel disulfide/graphene composite with enhanced electrochemical performance for reversible lithium storage[J].Journal of Power Sources,2015,294:51-58.
[29]RYU H S,KIM J S,PARK J,et al.Degradation mechanism of room temperature Na/Ni3S2 cells using Ni3S2 electrodes prepared by mechanical alloying[J].Journal of Power Sources,2013,244:764-770.
[30]GO D Y,PARK J,NOH P J,et al.Electrochemical properties of monolithic nickel sulfide electrodes for use in sodium batteries[J].Materials Research Bulletin,2014,58:190-194.
[31]秦伟.金属硫化物-石墨烯复合物的微波法制备及其在钠离子电池负极的应用[D].上海:华东师范大学,2016.QIN W.The microwave-assisted synthesis of metal sulfide-graphene composite for the anode of sodium-ion batteries[D].Shanghai:East China Normal University,2016.
[32]HOU B H,WANG Y Y,GUO J Z,et al.Pseudocapacitance-boosted ultrafast Na storage in a pie-like FeS@C nanohybrid as an advanced anode material for sodium-ion full batteries[J].Nanoscale,2018,10(19):9218-9225.