低黏度耐高温高强度环氧改性单组分聚氨酯胶粘剂的合成

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英文篇名：Synthesis of an epoxy resin modified polyurethane one-component adhesive with low-viscosity, high-temperature resistance and high-strength 作者：刘钾培 ; 张熙 ; 张军 ; 曹建强 英文作者：LIU Jia-pei;ZHANG Xi;ZHANG Jun;CAO Jian-qiang;Suzhou Jin Qiang New Material Co., Ltd.,Jiangsu Province Adhesive Engineering Technology Research Center; 关键词：环氧改性聚氨酯(EP-PU) ; 固化时间 ; 催化剂 ; 综合性能 英文关键词：epoxy resin modified polyurethane;;curing time;;catalyst;;comprehensive performance 中文刊名：NIAN 英文刊名：Adhesion 机构：苏州金枪新材料股份有限公司,江苏省胶粘剂工程技术研究中心;迪马新材料科技有限公司; 出版日期：2017-09-10 出版单位：粘接 年：2017 期：v.38;No.283 语种：中文; 页：NIAN201709010 页数：4 CN：09 ISSN：42-1183/TQ 分类号：53-56

摘要

采用环氧(E-51)改性聚氨酯(PU)的方法提高PU胶粘剂的性能。通过向PU中加入E-51制得具有低黏度高强度耐高温的环氧改性聚氨酯(EP-PU)单组分胶粘剂;由于E-51改性PU固化时间较长,故加入二月桂酸二丁基锡催化剂以缩短固化时间。研究了E-51和催化剂含量对胶粘剂固化时间、贮存期、强度以及耐热性的影响,以确定相对最佳的E-51和催化剂加入量,使改性后的胶粘剂综合性能达到相对最佳。
        The modification of polyurethane with epoxy resin E-51 is used to improve the properties of polyurethane adhesive in this paper. The epoxy resin modified polyurethane single-component adhesive(EP-PU) with low viscosity, high strength and high temperature resistance was prepared by adding the epoxy resin E-51 into polyurethane. The curing time of the epoxy resin modified polyurethane was too long, then the dibutyltin dilaurate catalyst was added into the EP-PU to shorten the curing time. The effects of different contents of epoxy resin and catalyst on the curing time, storage time, strength and heat resistance of the adhesive were studied. And the optimal amounts of epoxy resin and catalyst were selected to achieve beter comprehensive performance of the modified adhesive.

引文

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