氮化碳改性SnO_2复合光催化剂的制备及性能
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  • 英文篇名:Preparation of C_3N_4 modified SnO_2 composite photocatalyst and its properties
  • 作者:王睿源 ; 张新欣 ; 兰梦 ; 王宇 ; 董晓丽
  • 英文作者:WANG Ruiyuan;ZHANG Xinxin;LAN Meng;WANG Yu;DONG Xiaoli;School of Light Industry and Chemical Engineering, Dalian Polytechnic University;
  • 关键词:氮化碳 ; 氧化锡 ; 光催化 ; 水热法
  • 英文关键词:C_3N_4;;SnO_2;;photocatalytic;;hydrothermal method
  • 中文刊名:DLQG
  • 英文刊名:Journal of Dalian Polytechnic University
  • 机构:大连工业大学轻工与化学工程学院;
  • 出版日期:2019-03-15
  • 出版单位:大连工业大学学报
  • 年:2019
  • 期:v.38;No.166
  • 基金:国家自然科学基金项目(21476033)
  • 语种:中文;
  • 页:DLQG201902008
  • 页数:3
  • CN:02
  • ISSN:21-1560/TS
  • 分类号:31-33
摘要
以五水合四氯化锡、葡萄糖和尿素为原料,采用煅烧法及水热法制备合成了SnO_2/C_3N_4复合光催化剂。通过XRD、SEM、DRS等方法对合成的SnO_2/C_3N_4复合光催化剂进行表征。在可见光下,以罗丹明B为模拟污染物进行光催化降解实验,探讨了C_3N_4的引入对SnO_2/C_3N_4复合光催化剂的光催化性能的影响。结果表明,C_3N_4可以提高SnO_2在可见光下光催化性能,降解率由30%提高至70%。
        Hydrogen chloride and calcination method were used to synthesize SnO_2/C_3N_4 composite photocatalyst using tin tetrachloride pentahydrate, glucose and urea as raw materials. The synthesized SnO_2/C_3N_4 composite photocatalyst was characterized by XRD, SEM and DRS. The photocatalytic degradation of SnO_2/C_3N_4 was investigated using rhodamine B as simulated pollutant under visible light, and the effect of C_3N_4 on the photocatalytic activity of SnO_2/C_3N_4 composite photocatalysts was discussed. The results indicated that the introduction of C_3N_4 could improve the photocatalytic activity of SnO_2 under visible light, of which degradation rate increased from 30% to 70%.
引文
[1] LI Y, WANG H, FENG Q Y, et al. Gold nanoparticles inlaid TiO2 photoanodes: a superior candidate for high-efficiency dye-sensitized solar cells[J]. Energy Environmental Science, 2013, 6(7): 2156-2165.
    [2] ZHANG P, WANG L J, ZHANG X, et al. SnO2-core carbon-shell composite nanotubes with enhanced photocurrent and photocatalytic performance[J]. Applied Catalysis B: Environmental, 2015(166/167): 193-201.
    [3] WANG C, WANG X, XU B Q, et al. Enhanced photocatalytic performance of nanosized coupled ZnO/SnO2 photocatalysts for methyl orange degradation[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2004, 168(1): 47-52.
    [4] ZHAO Z W, SUN Y J, DONG F. Graphitic carbon nitride based nanocomposites: a review[J]. Nanoscale, 2015, 7(1): 15-37.
    [5] LI X F, LI M, YANG J H, et al. Synergistic effect of efficient adsorption g-C3N4/ZnO composite for photocatalytic property[J]. Journal of Physics and Chemistry of Solids, 2014, 75(3): 441-446.
    [6] YIN R, LUO Q Z, WANG D S, et al. SnO2/g-C3N4 photocatalyst with enhanced visible-light photocatalytic activity[J]. Journal of Materials Science, 2014, 49(17): 6067-6073.