水热炭的制备及其吸附应用的研究进展
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摘要
自然界中生物质资源丰富,但利用率很低,为了变废为宝,介绍了由生物质资源制备水热炭的方法。水热炭通常比表面积较大、孔隙度较高而表现出较好的吸附性,使其可以广泛地应用于吸附重金属离子和大气污染物。重点总结及讨论了对水热炭的4种化学改性方法,通过化学改性可提高其对重金属的吸附能力。
Biomass resources are abundant in nature, but the utilization rate is low, in order to make waste profitable, this paper introduces the method of hydrothermal carbonization of biomass resources to prepare hydrothermal carbon. The hydrothermal carbon has a better specific surface area, higher porosity and better adsorption capacity, and it can be widely used in the adsorption of heavy metal ions, atmospheric pollutants and so on. 4 chemical modification methods of hydrothermal carbon are summarized and discussed, which can improve the adsorption capacity of heavy metals.
Biomass resources are abundant in nature, but the utilization rate is low, in order to make waste profitable, this paper introduces the method of hydrothermal carbonization of biomass resources to prepare hydrothermal carbon. The hydrothermal carbon has a better specific surface area, higher porosity and better adsorption capacity, and it can be widely used in the adsorption of heavy metal ions, atmospheric pollutants and so on. 4 chemical modification methods of hydrothermal carbon are summarized and discussed, which can improve the adsorption capacity of heavy metals.
引文
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[2] Chen Z M,Chrn B L,Zhou D D,et al.Environmental Science & Technology,2012,46(22):12476-12483
[3] Harpreet S K,Animesh D.Renewable and Sustainable Energy Reviews,2015,45:359-378
[4] 陈温福,张伟明,孟军.中国农业科学,2013,46(16):3324-3333
[5] 张伟明.生物炭的理化性质及其在作物生产上的应用.沈阳:沈阳农业大学博士学位论文,2012
[6] IBI.Standardized product definition and product testing guidelines for biochar that is used in Soil.New York:International Biochar Initiative,2013:1-48
[7] Jin S C,Sung H P,Sang C J,et al.Journal of Industrial and Engineering Chemistry,2016,40:1-15
[8] 尉士俊,杨冬,时亦飞.节能,2015(1):59-61
[9] 吴晴雯,孟梁,张志豪,等.环境化学,2015,34 (9):1703-1709
[10] Bergius F.Nobel Foundation (Lecture Note).1931:1-33
[11] ?zbay N,Pütün A E,Uzun B B,et al.Renew Energy,2001,24:615-625
[12] Perlack R D,Wright L L,Turhollow A F,et al.Petroleum,2005,12(4):4
[13] Demirbas A.Energy Conversion Management,2001,42(10):1229-1238
[14] 张进红,林启美,赵小蓉,等.农业工程学报,2015,31(24):239-244
[15] Guo S Q,Dong X Y,Wu T T,et al.Energy Conversion and Management,2016,123:95-103
[16] 吴艳姣.生物质水热炭的制备及性能研究.哈尔滨:东北林业大学硕士学位论文,2016:15
[17] 张双杰,邢宝林,黄光许,等.化工进展,2016,35(3):950-956
[18] Fernandez M E,Ledesma B,Román S,et al.Bioresource Technology,2015,183:221-228
[19] Zhu X D,Liu Y C,Zhou C,et al.ACS Sustainable Chemistry & Engineering,2014,2:969-977
[20] Li Y,Li D W,Rao Y,et al.Carbon,2016,105:454-462
[21] Jimenez-Cordero D,Heras F,Alonso-Morales N,et al.Fuel Processing Technology,2015,139:42-48
[22] 黄艳,黄阳,王维清,等.新疆农业大学学报,2016,39(2):149-154
[23] Jelena T P,Mirjana D S,Jelena V M,et al.Journal of Environmental Management,2016,182:292-300
[24] 张越.功能化生物炭对溶液中重金属的增强吸附研究.武汉:武汉科技大学博士学位论文,2015:5
[25] 张敬华.化学世界,2016(1):16-29
[26] 陈靖,李伟民,丁文川,等.环境工程学报,2015,9(11):5187-5192
[27] Tang Z,Deng Y F,Luo T.Chemical Engineering Journal,2016,292:224-232
[28] Zhang J,Lin Q,Zhao X.Journal of Integrative Agriculture,2014,13(3):471-482
[29] Kang S,Li X,Fan J,et al.Bioresource Technology,2012,110:715-718
[30] Poerschmann J,Weiner B,Baskyr I.Chemosphere,2013,92(11):1472-1482
[31] Hwang I H,Aoyama H,Matsuto T,et al.Waste Management,2012,32(3):410-416