生漆与腰果漆
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摘要
生漆源于自然,生物合成,主要由漆酚、多糖类化合物、漆酶、水分等组成,是一种性能优异的天然树脂;腰果漆主要由腰果酚与苯酚、甲醛等有机合成。腰果酚结构与漆酚结构类似,同属于酚类化合物。本文从生漆与腰果漆的组分、结构性能、成膜机理等方面详细介绍了生漆与腰果漆的区别,说明了腰果漆并不是合成大漆。
Chinese lacquer which is from the natural and biosynthesis,is mainly composed of urushiol,polysaccharide compounds,laccase,moisture and so on.It is a kind of natural resin with excellent performance.Cashew paint is mainly composed of cashew phenol,phenol and formaldehyde by organic synthesis.The structure of Cashew phenol is similar to urushiol,both belong to the phenolic compounds.This article introduced the difference between the raw lacquer and cashew paint in detail,which from the composition,structure performance and film-forming mechanism between raw lacquer and cashew paint.It illustrates the cashew paint is not synthetic Chinese lacquer.
Chinese lacquer which is from the natural and biosynthesis,is mainly composed of urushiol,polysaccharide compounds,laccase,moisture and so on.It is a kind of natural resin with excellent performance.Cashew paint is mainly composed of cashew phenol,phenol and formaldehyde by organic synthesis.The structure of Cashew phenol is similar to urushiol,both belong to the phenolic compounds.This article introduced the difference between the raw lacquer and cashew paint in detail,which from the composition,structure performance and film-forming mechanism between raw lacquer and cashew paint.It illustrates the cashew paint is not synthetic Chinese lacquer.
引文
[1]赵喜萍,魏朔南.中国生漆化学成分研究[J].中国野生植物资源,2007,26(6):1-4.
[2]甘景镐.如何从古老的国宝涂料转变新型的化工材料[J].中国生漆,1992,(1):10-15.
[3]Piyali Das,Anuradda Ganesh,Bio-oil.From pyrolysis of cashewnut shell-A new fuel[J].Biomass Bioenersy,2003,25:113-117.
[4]Rajesh N Patel,Santanu Bandyopadhyay,Anuradda Ganesh.Economic appraisal of supercritical fluid extraction of refined cashew nut shell liquid[J].Chromatography A,2006,24:130-138.
[5]杜克敏.腰果市场及腰果壳液在涂料中的应用[J].中国涂料,2004,45(10):45-48.
[6]金保宏,王柏臣,陈平等.BMI改性腰果壳油-酚醛树脂的热性能[J].合成树脂及塑料,2010,27(2):55-57.
[7]赵一庆.生漆及漆树资源[J].中国林业出版社,2003,(1):55-62.
[8]张飞龙.漆成膜的分子基础-Ⅰ生漆成膜的物质基础[J].2010,(1):26-44.
[9]万云洋.漆酶结构与催化机理[J].化学通报,2007,(4):662-670.
[10]季立才.漆酶催化氧化反应研究进展[J].林产化学与工业,1997,17(1):79-84.
[11]张飞龙.生漆精制过程对漆液流变性质的影响研究[J].林产化学与工业,2007,28(4):81-85.
[12]李昕,石玉,张飞龙.生漆精制过程影响因子研究[J].中国生漆2006,(2):8-12.
[13]张飞龙.生漆的组成结构与其性能的关系研究[J].中国生漆2000,19(3):31-12.
[14]骆鹏,李翔.扬州漆器[M].南京:江苏人民出版社,2009:75-76.
[15]周昊.生漆中漆酚单体分离、化学结构修饰及生物活性研究进展[J].2017,51(1):44-50.
[16]潘宇.漆树的现代研究进展[J].科技导报,2013,31(26):74-78.
[17]胡家朋,熊联明,沈震.腰果壳油的蒸馏及馏分成分研究[J].应用化工,2007,36(4):345-351.
[18]刘小英,腰果酚基聚合物的研究[D].福建师范大学,2004.
[19]张飞龙,陈振锋等.秦巴山区漆树资源可持续发展及规模化管理模式研究[J].中国生漆,2004,23(1):1-27.
[20]张飞龙.生漆成膜聚合过程[J].涂料工业,1993,(4):40-46.
[21]张飞龙.中国髹漆工艺与漆器保护[M].北京:科学出版社,2010:277-278.
[22]朱贵明浅谈室内甲醛待集及消除方法[J].农村经济与科技,2012.23(5):127-128.
[23]陈贻炽,王红山,赵学航,等.梗如坚果壳液的制取化学性质及应[J].四川化工,1997(3):54-58.
[24]广州腰果壳液涂料研制协作组.腰果酚醛树脂及漆的试验[J].涂料工业,1978,(2):10-16.
[25]孙祥玲,生漆改性及其应用进展[J].生物质化学工程,2014,48(2):42-47.
[26]贺娜,张飞龙.漆树资源、环境与人类文化[J].中国生漆2011,30(4):17-20.
[27]张飞龙,李钢.生漆的组成结构与其性能的关系研究[J].中国生漆,2000,19(3):31-37.
[28]钞亚鹏,钱世钧.真菌漆酶及其应用.生物工程进展.2001,21(5):23-28.
[2]甘景镐.如何从古老的国宝涂料转变新型的化工材料[J].中国生漆,1992,(1):10-15.
[3]Piyali Das,Anuradda Ganesh,Bio-oil.From pyrolysis of cashewnut shell-A new fuel[J].Biomass Bioenersy,2003,25:113-117.
[4]Rajesh N Patel,Santanu Bandyopadhyay,Anuradda Ganesh.Economic appraisal of supercritical fluid extraction of refined cashew nut shell liquid[J].Chromatography A,2006,24:130-138.
[5]杜克敏.腰果市场及腰果壳液在涂料中的应用[J].中国涂料,2004,45(10):45-48.
[6]金保宏,王柏臣,陈平等.BMI改性腰果壳油-酚醛树脂的热性能[J].合成树脂及塑料,2010,27(2):55-57.
[7]赵一庆.生漆及漆树资源[J].中国林业出版社,2003,(1):55-62.
[8]张飞龙.漆成膜的分子基础-Ⅰ生漆成膜的物质基础[J].2010,(1):26-44.
[9]万云洋.漆酶结构与催化机理[J].化学通报,2007,(4):662-670.
[10]季立才.漆酶催化氧化反应研究进展[J].林产化学与工业,1997,17(1):79-84.
[11]张飞龙.生漆精制过程对漆液流变性质的影响研究[J].林产化学与工业,2007,28(4):81-85.
[12]李昕,石玉,张飞龙.生漆精制过程影响因子研究[J].中国生漆2006,(2):8-12.
[13]张飞龙.生漆的组成结构与其性能的关系研究[J].中国生漆2000,19(3):31-12.
[14]骆鹏,李翔.扬州漆器[M].南京:江苏人民出版社,2009:75-76.
[15]周昊.生漆中漆酚单体分离、化学结构修饰及生物活性研究进展[J].2017,51(1):44-50.
[16]潘宇.漆树的现代研究进展[J].科技导报,2013,31(26):74-78.
[17]胡家朋,熊联明,沈震.腰果壳油的蒸馏及馏分成分研究[J].应用化工,2007,36(4):345-351.
[18]刘小英,腰果酚基聚合物的研究[D].福建师范大学,2004.
[19]张飞龙,陈振锋等.秦巴山区漆树资源可持续发展及规模化管理模式研究[J].中国生漆,2004,23(1):1-27.
[20]张飞龙.生漆成膜聚合过程[J].涂料工业,1993,(4):40-46.
[21]张飞龙.中国髹漆工艺与漆器保护[M].北京:科学出版社,2010:277-278.
[22]朱贵明浅谈室内甲醛待集及消除方法[J].农村经济与科技,2012.23(5):127-128.
[23]陈贻炽,王红山,赵学航,等.梗如坚果壳液的制取化学性质及应[J].四川化工,1997(3):54-58.
[24]广州腰果壳液涂料研制协作组.腰果酚醛树脂及漆的试验[J].涂料工业,1978,(2):10-16.
[25]孙祥玲,生漆改性及其应用进展[J].生物质化学工程,2014,48(2):42-47.
[26]贺娜,张飞龙.漆树资源、环境与人类文化[J].中国生漆2011,30(4):17-20.
[27]张飞龙,李钢.生漆的组成结构与其性能的关系研究[J].中国生漆,2000,19(3):31-37.
[28]钞亚鹏,钱世钧.真菌漆酶及其应用.生物工程进展.2001,21(5):23-28.