挥发性有机物催化氧化技术及催化剂研究进展
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摘要
近年来,随着生态环境的逐渐恶化,挥发性有机物的污染治理越来越受到社会各界专家和学者的广泛重视。挥发性有机物的治理技术主要包括吸附技术等回收技术和催化氧化技术等破坏技术,催化氧化是处理挥发性有机物的一种较为彻底的技术,具有能耗低、无二次污染、安全性好和适用范围广等优点。通过对挥发性有机物处理技术,催化氧化机理和挥发性有机物氧化催化剂等几个方面的介绍,旨在推动挥发性有机物治理特别是催化氧化技术的进展。
In recent years,with the gradual deterioration of the ecological environment,the pollution control of volatile organic compounds has received more and more attention from experts and scholars from all walks of life.The treatment technology of volatile organic compounds mainly includes recovery technologies such as adsorption technology and destruction technologies such as catalytic oxidation technology.Catalytic oxidation is a more thorough technique for the treatment of volatile organic compounds. It has the advantages of low energy consumption,no secondary pollution,good safety and wide application range.The introduction of volatile organic compounds treatment technology,catalytic oxidation mechanism and volatile organic oxidation catalysts is aimed at promoting the development of volatile organic compounds,especially catalytic oxidation technology.
In recent years,with the gradual deterioration of the ecological environment,the pollution control of volatile organic compounds has received more and more attention from experts and scholars from all walks of life.The treatment technology of volatile organic compounds mainly includes recovery technologies such as adsorption technology and destruction technologies such as catalytic oxidation technology.Catalytic oxidation is a more thorough technique for the treatment of volatile organic compounds. It has the advantages of low energy consumption,no secondary pollution,good safety and wide application range.The introduction of volatile organic compounds treatment technology,catalytic oxidation mechanism and volatile organic oxidation catalysts is aimed at promoting the development of volatile organic compounds,especially catalytic oxidation technology.
引文
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[32]WANG R H,LI J H.Effects of precursor and sulfation on OMS-2 catalyst for oxidation of ethanol and acetaldehyde at low temperatures[J]. Environ. Sci. Technol.,2010,44(11):4 282-4 287.
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[35]DAI H X,HE H,LI P H,et al.The relationship of structural defect-redox property-catalytic performance of perovskites and their related compounds for CO and NOx removal[J].Catal.Today,2004,90(3/4):231-244.
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[37]DENG J G,DAI H X,JIANG H Y,et al.Hydrothermal fabrication and catalytic properties of La1-xSrxM1-yFeyO3(M=Mn,Co)that are highly active for the removal of toluene[J]. Environ. Sci. Technol.,2010,44(7):2 618-2 623.
[38]IRUSTA S,PINA M P,MENNDEZ M,et al. Catalytic combustion of volatile organic compounds over La-based perovskites[J].J.Catal.,1998,179(2):400-412.
[39]ASADA T,KAYAMA T,KUSABA H,et al.Preparation of alumina-supported La Fe O3catalysts and their catalytic activity for propane combustion[J]. Catal. Today,2008,139(1/2):37-42.
[2]封跃鹏,邱赫男,房丽萍,等.甲醇中25种VOCs混合溶液标准样品制备技术研究[J].化学试剂,2015,37(12):1 152-1 156.
[3]李正林,薛屏.用反相微乳法制备二甲苯燃烧催化剂Cu MnOx[J].宁夏大学学报,2008,29(1):56-60.
[4]WEI W,WANG S X,CHATANI S,et al. Emission and speciation of non-methane volatile organic compounds from anthropogenic sources in China[J].Atmos.Environ.,2008,42(2):4 976-4 988.
[5]XIE S D.Spatial and temporal variation of historical anthropogenic NM VOCs emission inventories in China[J].Atmos.Chem.Phys.,2008,8:7 297-7 316.
[6]PIRES J,CARVALHO A,CARVALHO M B. Adsorption of volatile organic compounds in Y zeolites and pillared clays[J].Micropor.Mesopor.Mat.,2001,43(3):277-280.
[7]ZHAO J,YANG X D.Photocatalytic oxidation for indoor air purification:a literature review[J]. Build. Environ.,2003,38(5):645-654.
[8]ENGLEMAN V S.Updates on choices of appropriate technology for control of VOC emissions[J].T.I.Met.Finish.,2000,98(6):433-450.
[9]MOON H S,KIM I S,KANG S J,et al.Adsorption of volatile organic compounds using activated carbon fiber filter in the automobiles[J]. Carbon Lett.,2014,15(3):203-209.
[10]中国环境保护产业协会废气净化委员会.我国有机废气治理行业2010年发展综述[J].中国环保产业,2011,8:8-15.
[11]CLOIREC P L.Treatments of polluted emissions from incinerator gases:a succinct review[J]. Rev. Environ. Sci.Bio.,2012,11(4):381-392.
[12]栾志强,郝郑平,王喜芹.工业固定源VOCs治理技术分析评估[J].环境科学,2011,32(12):3 476-3 486.
[13]王艳芳,沙昊泪,於建明.低浓度VOCs废气处理技术进展[J].能源环境保护,2007,21(3):8-12.
[14]ZHANG Z X,JIANG Z,SHANGGUAN W F. Low-temperature catalysis for VOCs removal in technology and application:a state-of-the-art review[J]. Catal. Today,2016,264:270-278.
[15]刘媛,龙千明,白云鹤,等.Ti O2-Si O2/Zr O2催化剂的制备及催化燃烧甲苯性能[J].化工进展,2009,29(11):2 090-2 102.
[16]苏孝文.Pd/CexCu1-xO2-δ-Y2O3整体式催化剂的制备及其氧化性能研究[D].金华:浙江师范大学,2009.
[17]GANDIA L M,GIL A,KORILI S A.Effects of various alkali-acid additives on the activity of a manganese oxide in the catalytic combustion of ketones[J].Appl.Catal.BEnviron.,2001,33(1):1-8.
[18]SPIVEY J J.Complete catalytic oxidation of volatile organics[J]. Ind. Eng. Chem. Res.,1987,26(11):2 165-2 180.
[19]PENG J X,WANG S D. Performance and characterization of supported metal catalysts for complete oxidation of formaldehyde at low temperatures[J]. Appl. Catal. BEnviron.,2007,73(3/4):282-291.
[20]SEKIZAWA K,WIDJAJA H,MAEDA S,et al.Low temperature oxidation of methane over Pd/Sn O2catalyst[J].Appl.Catal.A-Gen.,2000,200(1/2):211-217.
[21]HUANG H B,HU P,HUANG H L,et al.Highly dispersed and active supported Pt nanoparticles for gaseous formaldehyde oxidation:influence of particle size[J].Chem.Eng.J.,2014,252:320-326.
[22]陈春雨.沸石分子筛负载Pt的挥发性有机物(VOCs)催化消除[D].杭州:浙江大学,2015.
[23]薛彬.Pd基天然气催化燃烧催化剂硫中毒行为的研究[D].北京:北京工业大学,2007.
[24]MARCOT P,FAKCHE A,KELLALI B,et al.Propane and propene oxidation over platinum and palladium on alumina:effects of chloride and water[J].Appl.Catal. BEnviron.,1994,3(4):283-294.
[25]REN Y,MA Z,QIAN L P,et al.Ordered crystalline mesoporous oxides as catalysts for CO oxidation[J].Catalysis Lett.,2009,131(1/2):146-154.
[26]李容,郑国钧,赵秀芳,等.催化分子氧氧化醇类的研究进展[J].化学试剂,2005,27(8):459-463.
[27]KIM S C,SHIM W G.Catalytic combustion of VOCs over a series of manganese oxide catalysts[J]. Appl. Catal. BEnviron.,2010,98(3/4):180-185.
[28]PAN H Y,LI Z,XIA Q B,et al.Catalytic activity of copper based catalysts pretreated with H2reduction for catalytic combustion of styrene[J]. Catal. Commun.,2009,10(8):1 166-1 169.
[29]YANG J S,JUNG W Y,LEE G D,et al.Catalytic combustion of benzene over metal oxides supported on SBA-15[J].J.Ind.Eng.Chem.,2008,14(6):779-784.
[30]PENA M A,FIERRO J L G. Chemical structures and performance of perovskite oxides[J]. Chem. Rev.,2001,101(7):1 981-2 018.
[31]CARRILLO A M,CARRIAZO J G. Cu and Co Oxides supported on halloysite for the total oxidation of toluene[J].Appl.Catal.B-Environ.,2015,164:443-452.
[32]WANG R H,LI J H.Effects of precursor and sulfation on OMS-2 catalyst for oxidation of ethanol and acetaldehyde at low temperatures[J]. Environ. Sci. Technol.,2010,44(11):4 282-4 287.
[33]HU C Q,ZHU Q S,JIANG Z,et al.Preparation and formation mechanism of mesoporous Cu O-CeO2mixed oxides with excellent catalytic performance for removal of VOCs[J]. Micropor. Mesopor. Mat.,2008,113(1/3):427-434.
[34]LIAO Y N,FU M L,CHEN L M,et al.Catalytic oxidation of toluene over nanorod-structured Mn-Ce mixed oxides[J].Catal.Today,2013,216:220-228.
[35]DAI H X,HE H,LI P H,et al.The relationship of structural defect-redox property-catalytic performance of perovskites and their related compounds for CO and NOx removal[J].Catal.Today,2004,90(3/4):231-244.
[36]BLASIN-AUBV,BELKOUCH J,MONCEAUX L.General study of catalytic oxidation of various VOCs over La0.8Sr0.2MnO3+xperovskite catalyst-influence of mixture[J].Appl.Catal.B-Environ.,2003,43(2):175-186.
[37]DENG J G,DAI H X,JIANG H Y,et al.Hydrothermal fabrication and catalytic properties of La1-xSrxM1-yFeyO3(M=Mn,Co)that are highly active for the removal of toluene[J]. Environ. Sci. Technol.,2010,44(7):2 618-2 623.
[38]IRUSTA S,PINA M P,MENNDEZ M,et al. Catalytic combustion of volatile organic compounds over La-based perovskites[J].J.Catal.,1998,179(2):400-412.
[39]ASADA T,KAYAMA T,KUSABA H,et al.Preparation of alumina-supported La Fe O3catalysts and their catalytic activity for propane combustion[J]. Catal. Today,2008,139(1/2):37-42.