环境中有机污染物检测技术研究进展
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摘要
以环境中有机污染物的检测技术为出发点,将环境中有机污染物分类为挥发性有机污染物、半挥发性有机污染物、持久性有机污染物、抗生素和有机锡化合物。分类概述了五类有机污染物的前处理技术应用现状,并进一步阐述了这五类污染物的检测技术研究现状,为未来环境中有机污染物检测技术的深入研究提供参考依据。
According to the detection of organic pollutants in environment,the organic pollutants are divided into volatile organic compounds,semi volatile organic compounds,persistent organic pollutants,antibiotics,and organotin compounds. The application status of pre-treatment technique has been summarized respectively,and the research status of detection technique has also been further expounded. It will provide a reference for further study on the detection technology of organic pollutants in environment.
According to the detection of organic pollutants in environment,the organic pollutants are divided into volatile organic compounds,semi volatile organic compounds,persistent organic pollutants,antibiotics,and organotin compounds. The application status of pre-treatment technique has been summarized respectively,and the research status of detection technique has also been further expounded. It will provide a reference for further study on the detection technology of organic pollutants in environment.
引文
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[2]邵敏,董东.我国大气挥发性有机物污染与控制[J].环境保护,2013(5):25-28.
[3] Yu B F,Song Y H,Han L,et al. Optimizations of packed sorbent and inlet temperature for large volume-direct aqueous injection-gas chromatography to determine high boiling volatile organic compounds in water[J]. Journal of Chromatography A,2014,1356:221-229.
[4]徐庆娟,冯宇辉,吴学.顶空单滴液相微萃取与GC-MS联用测定易挥发溶剂[J].延边大学学报:自然科学版,2011,37(2):144-147.
[5] Maia R,Correia M,Pereira I M,et al. Optimization of HSSPME analytical conditions using factorial design for trihalomethanes determination in swimming pool water samples[J]. Microchemucal Journal,2014,112:167-171.
[6] Mesarchaki E,Yassaa N,Hein D,et al. A novel method for the measurement of VOCs in seawater using needle trap devices and GC-MS[J]. Marine Chemistry,2014,159:1-8.
[7]宋洲,杨杰,董学林,等. P&T-GC-MS联用技术测定地下水中挥发性有机污染物[J].安全与环境工程,2017,24(1):88-94.
[8]吴宇峰,李利荣,时庭锐,等.大气总悬浮颗粒物中半挥发性有机污染物的测定[J].安全与环境学报,2006,6(3):86-89.
[9]吕天峰,张宝,滕恩江,等.固相微萃取-气相色谱-质谱法测定水体中半挥发性有机污染物[J].理化检验(化学分册),2013,49(8):957-960.
[10]邢凤琴,张志强,杨贤智.河水中半挥发性有机物测定方法的研究[J].同济大学学报:医学版,2001,22(2):10-12.
[11]叶伟红,潘荷芳,刘劲松,等.地表水中半挥发性有机物的固相萃取GC-MS方法研究[J].中国环境监测,2010,26(4):40-44.
[12]李春玉,戴玄吏.固相微萃取-气相色谱法测定水源地水中半挥发性有机污染物[C]. 2010中国环境科学学会学术年会论文集(第二卷).上海:中国环境科学学会,2010.
[13]于慧芳,朱志琴,赵旭东,等. 1998年北京市4城区人乳有机氯农药(DDT、666)污染水平[J].中国公共卫生,2001,17(8):735-736.
[14] Michael S Y,Kim V T. OASIS(R)WAX固相提取吸附剂用于水及组织中PFOS和相关化合物的UPLC(R)/MS定量分析[J].环境化学,2007,26(1):119-121.
[15] Villaverde-de-Saa E,Quintana J B. Determination of perfluorinated compounds in mollusks by matrix solid-phase dispersion and liquid chromatography-tandem mass spectrometry[J]. Analytical and Bioanalytical Chemistry,2012,402(1):509-518.
[16] Beser M I,Pardo O. Determination of per and polyfluorinated substances in airborne particulate matter by microwaveassisted extraction and liquid chromatography-tandem mass spectrometry[J]. Journal of Chromatography A,2011,1218(30):4847-4855.
[17]罗慧,王新红,汤丽,等.中国部分沿海海域还与水体中溶解态有机氯农药和多氯联苯的残留分布特征[J].海洋环境科学,2010,29(1):115-120.
[18]李卫东.持久性有机污染物的研究进展[J].石油化工应用,2009,28(6):1-4.
[19]戚佳琳.工业产品与生态环境中有机锡化合物的形态分析与应用研究[D].青岛:中国海洋大学,2013.
[20] Nikolaou A D,Gatidou G M,Golfnopoulos S K,et al. A one-year survey of organotin compounds in the reservoirs supplying the drinking water treatment plants of Athens,Greece[J]. Desalination,2007,210:24-30.
[21] Wang X P,Ding L,Zhang H R,et al. Development of an analytical method for organotin compounds in fortified flour samples using microwave-assisted extraction and normalphase HPLC with UV detection[J]. Chromatography B,2006,843:268-274.
[22] Qian M R,Zhang H,Wu L Q,et al. Simultaneous determination of zearalenone and its derivatives in edible vegetable oil by gel permeation chromatography and gas chromatography-triple quadrupole mass spectrometry[J]. Food Chemistry,2015,166:23-28.
[23] Gallego-Gallegos M,Muňoz-Olivas R,Cmara C. Different formats of imprinted polymers for determining organotin compounds in environmental samples[J]. Environmental Management,2009,90:S69-S76.
[24]胡贵祥,万益群,朱慧芳. SPME-GC/MS在线衍生测定尿液中多种有机锡化合物[J].南昌大学学报:理科版,2015,39(5):463-467.
[25]毛雪金,李娟,万益群.超声波提取-分散固相萃取净化-气相色谱法测定紫菜中三丁基锡和三苯基锡[J].分析科学学报,2012,28(6):757-761.
[26]林鋆,朱峰,王明葵.加速溶剂萃取-高效液相色谱-电感耦合等离子体质谱法测定聚乳酸材料中4种有机锡化合物[J].质谱学报,2014,35(5):454-461.
[27] Zachariadis G A,Rosenberg E. Speciation of organotin compounds in urine by GC-MIP-AED and GC-MS after ethylation and liquid-liquid extraction[J]. Chromatography B,2009,877:1140-1144.
[28]祁彦洁,刘菲.地下水中抗生素污染检测分析研究进展[J].岩矿测试,2014,33(1):1-11.
[29] Tsai W H,Huang T C,Huang J J,et al. Dispersive solidphase microextraction method for sample extraction in the analysis of four tetracyclines in water and milk samples by high-performance liquid chromatography with diodearray detection[J]. J Chromatogr A,2009,1216(12):2263-2269.
[30]应悦汉,王婧,吴昊,等. RP-HPLC法测定水体表层沉积物中的磺胺类与四环素类抗生素[J].分析测试学报,2016,35(10):1311-1316.
[31]刘思思,杜鹃,陈景文,等.加速溶剂萃取-高效液相色谱-串联质谱联用测定莱州湾海水养殖区野生鱼肌肉中19种抗生素及2种磺胺代谢产物残留[J].色谱,2014,32(12):1320-1325.
[32]徐晖,吴明红,徐刚.高效液相色谱-串联质谱法对水环境中12种抗生素的检测[J].上海大学学报:自然科学版,2017,23(3):483-490.
[33]国明,于峰,贾科玲,等.磁性固相萃取-高效液相色谱-串联质谱法测定环境水样中的四环素类抗生素[J].色谱,2016,34(4):407-413.
[34]杨光,徐晓波,高德玉,等.分子印迹固相萃取技术在抗生素检测中的应用进展[J].黑龙江科学,2015,6(17):56-57.
[35]王敏,李波,刘超,等.双水相萃取-LC-MS/MS同时测定环境水中11种抗生素[J].广州化工,2016,44(22):73-77.
[36] Meng M H,He Z Y,Xu Y P,et al. Simultaneous extraction and determination of antibiotics in soils using a QECh ERS-based method and liquid chromatography-tandem mass spectrometry[J]. Journal of Ago-Environment Science,2017,36(8):1672-1679.
[37]李明月,孙倩,王琴,等.污泥中典型抗生素的检测[J].环境工程学报,2016,10(2):985-991.
[38]占美君,赖永忠.静态顶空-气相色谱/质谱法同时检测环境水体中59种挥发性有机物[J].分析测试技术与仪器,2016,22(4):250-260.
[39]冯丽丽,胡晓芳,于晓娟,等.热脱附-气相色谱-三重四极杆串联质谱法测定环境空气中的挥发性有机物[J].色谱,2016,34(2):209-214.
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