聚苯胺在防腐方面的研究及应用现状
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摘要
聚苯胺(PANI)具有良好的热稳定性和环境稳定性,经掺杂后,具有导电性及电化学性,可作为填料应用于金属防腐领域。但其分子链骨架刚性强、分子间作用力大,不易加工成型,不溶于常规的有机溶剂,当其作为填料应用到防腐涂料中存在溶解性、分散性差且与金属基底附着力不强等缺点,如能对其进行合理有效的改性,则可解决上述问题。简要探讨了溶液聚合法、反相微乳液聚合法、模板聚合法以及电化学聚合法等PANI的制备方法,并针对PANI在防腐涂料应用中存在的问题,重点阐述了PANI的质子酸掺杂改性及复合改性等不同改性方法,通过掺杂不同的质子酸对PANI进行化学改性,可降低PANI分子链之间的相互作用,从而提高其溶解性、导电性和防腐性能。将不同性能的材料与PANI进行复合改性,改善分子间作用力,能提高其加工性,从而更好的应用于金属的腐蚀防护工作。最后介绍了PANI在腐蚀防护过程中的作用、在防腐蚀涂料中的应用及相关理论的研究现状,并指出PANI防腐涂层的研究重点和发展方向。
Polyaniline(PANI) has good thermal stability and environmental stability, and can be doped with conductive and electrochemical properties and used as a filler in the field of metal corrosion protection due to conductivity and electrochemical property. However, Polyaniline is difficult to be processed and formed due to strong rigidity in molecular chain skeleton and large intermolecular forces. Polyaniline is insoluble in conventional organic solvents and has poor solubility, poor dispersibility, and poor adhesion to metal substrates when used as filler. If reasonably and effectively modified, Polyaniline can solve the above problems. The preparation methods of PANI such as solution polymerization, reverse microemulsion polymerization, template polymerization and electrochemical polymerization were briefly discussed. The problems of PANI in the application of anticorrosion coatings were discussed, and different modification methods such as proton acid doping of PANI and compound modification were highlighted. Chemical modification of PANI by doping with different protonic acids could reduce the interaction between PANI molecular chains, thereby increasing the solubility, conductivity and corrosion resistance. The composite modification of PANI by materials with different properties could improve the intermolecular forces and the processability, and could be applied to the corrosion protection of metals better. Finally, the role of PANI in the corrosion protection process, the application of PANI in anti-corrosion coatings and related research theories are described, and the research emphasis and development direction of PANI anticorrosive coatings are pointed out.
Polyaniline(PANI) has good thermal stability and environmental stability, and can be doped with conductive and electrochemical properties and used as a filler in the field of metal corrosion protection due to conductivity and electrochemical property. However, Polyaniline is difficult to be processed and formed due to strong rigidity in molecular chain skeleton and large intermolecular forces. Polyaniline is insoluble in conventional organic solvents and has poor solubility, poor dispersibility, and poor adhesion to metal substrates when used as filler. If reasonably and effectively modified, Polyaniline can solve the above problems. The preparation methods of PANI such as solution polymerization, reverse microemulsion polymerization, template polymerization and electrochemical polymerization were briefly discussed. The problems of PANI in the application of anticorrosion coatings were discussed, and different modification methods such as proton acid doping of PANI and compound modification were highlighted. Chemical modification of PANI by doping with different protonic acids could reduce the interaction between PANI molecular chains, thereby increasing the solubility, conductivity and corrosion resistance. The composite modification of PANI by materials with different properties could improve the intermolecular forces and the processability, and could be applied to the corrosion protection of metals better. Finally, the role of PANI in the corrosion protection process, the application of PANI in anti-corrosion coatings and related research theories are described, and the research emphasis and development direction of PANI anticorrosive coatings are pointed out.
引文
[1]ZHAO Y,ZHANG Z,YU L,et al.Hydrophobic polystyrene/electro-spun polyaniline coatings for corrosion protection[J].Synthetic metals,2017,234:166-174.
[2]程佳,孙锦辉,杜猛.对金属材料的腐蚀与防护分析[J].中国科技投资,2016(9):187.CHENG Jia,SUN Jin-hui,DU Meng.Analysis of corrosion and protection of metal materials[J].China science and technology investment,2016(9):187.
[3]NAZEER A A,MADKOUR M.Potential use of smart coatings for corrosion protection of metals and alloys:Areview[J].Journal of molecular liquids,2018,253:11-22.
[4]刘永超,赵雄燕,王鑫,等.防腐涂料的研究进展[J].化工新型材料,2016(4):38-40.LIU Yong-chao,ZHAO Xiong-yan,WANG Xin,et al.Research progress of anticorrosion coatings[J].New chemical materials,2016(4):38-40.
[5]王霞,唐佳,陈玉祥,等.流速对L360管线钢在H2S/CO2环境中腐蚀行为的影响[J].表面技术,2018,47(2):157-163.WANG Xia,TANG Jia,CHEN Yu-xiang,et al.Effect of flow velocity on corrosion behavior of L360 pipeline steel in H2S/CO2 environment[J].Surface technology,2018,47(2):157-163.
[6]KOHL M,KALENDOVA A,CERNOSKOVA E,et al.Corrosion protection by organic coatings containing polyaniline salts prepared by oxidative polymerization[J].Journal of coatings technology&research,2017,14(6):1-14.
[7]LI Z,SHEN Y,LI Y,et al.Doping effects of cerium ion on structure and electrochemical properties of polyaniline[J].Polymer international,2018,67(1):121-126.
[8]KURBATOV V G,INDEIKIN E A.Anticorrosion pigments with a shell of doped polyaniline[J].Protection of metals&physical chemistry of surfaces,2017,53(2):329-334.
[9]ZHANG Y,SHAO Y,LIU X,et al.A study on corrosion protection of different polyaniline coatings for mild steel[J].Progress in organic coatings,2017,111:240-247.
[10]CALDONA E B,DE LEON A C C,PAJARITO B B,et al.Novel anti-corrosion coatings from rubber-modified polybenzoxazine-based polyaniline composites[J].Applied surface science,2017,422:162-171.
[11]LIAO Z J,LIN C X,YANG C J,et al.Study on the preparation and electrochemical properties of nano ZnO/polyaniline composite anticorrosive coating[C]//Proceedings of the 2016 international conference on advances in energy,environment and chemical science,[s.l]:Atlantis Press,2016,76:294-298.
[12]DEBERRY D W.Modification of the electrochemical and corrosion behavior of stainless steels with an electroactive coating[J].Chem inform,1985,16(37):917-926.
[13]张静,冯玉坤,万小梅,等.导电聚苯胺的制备及其在防腐涂料中的应用[J].现代涂料与涂装,2011,14(3):12-14.ZHANG Jing,FENG Yu-kun,WAN Xiao-mei,et al.Preparation of conductive polyaniline and its application in anti-corrosion coatings[J].Modern coatings&coating,2011,14(3):12-14.
[14]HAFIZAH M A E,BIMANTORO A,ANDREAS,et al.Synthesized of conductive polyaniline by solution polymerization technique[J].Procedia chemistry,2016,19:162-165.
[15]夏小倩,沈玉芳,郭文勇,等.乳液聚合法合成聚苯胺材料进展[J].甘肃石油和化工,2010,24(4):1-5.XIA Xiao-qian,SHEN Yu-fang,GUO Wen-yong,et al.Progress in the synthesis of polyaniline materials by emulsion polymerization[J].Gansu petroleum&chemical industry,2010,24(4):1-5.
[16]WU Y J,HO K S,CHENG Y W,et al.Studies on the synthesis of low molecular weight,one-dimensional polyanilines prepared by fast emulsion polymerization using HCl/(n-Dodecylbenzenesulfonic acid)emulsifiers[J].Polymer international,2013,62(4):581-590.
[17]WANG Y,CHEN K,LI T,et al.Soluble polyaniline nanofibers prepared via surfactant-free emulsion polymerization[J].Synthetic metals,2014,198:293-299.
[18]PERRIN F X,PHAN T A,NGUYEN D L.Synthesis and characterization of polyaniline nanoparticles in phosphonic acid amphiphile aqueous micellar solutions for waterborne corrosion protection coatings[J].Journal of polymer science part A:Polymer chemistry,2015,53(13):1606-1616.
[19]ZHOU H H,FANG C X,YE T T,et al.Electrochemical synthesis of polyaniline in reverse microemulsion[J].Journal of Central South University,2014,21(11):4071-4075.
[20]ULLAH R,BILAL S,SHAH A U H A,et al.Synthesis and characterization of polyaniline doped with polyvinyl alcohol by inverse emulsion polymerization[J].Synthetic metals,2016,222:162-169.
[21]WANG X Y,LIU C Y,MIAO L,et al.Improving the thermoelectric properties of polyaniline by introducing poly(3,4-ethylenedioxythiophene)[J].Journal of electronic materials,2016,45(3):1813-1820.
[22]王国祥,刘鹏丽.反相微乳液聚合法合成聚苯胺[J].合成树脂及塑料,2011,28(2):23-26.WANG Guo-xiang,LIU Peng-li.Synthesis of polyaniline by reverse microemulsion polymerization[J].Synthetic resins&plastics,2011,28(2):23-26.
[23]GORDANA C M.Recent advances in polyaniline research:Polymerization mechanisms,structural aspects,properties and applications[J].Synthetic metals,2013,177:1-47.
[24]YIN C,GAO L,ZHOU F,et al.Facile synthesis of polyaniline nanotubes using self-assembly method based on the hydrogen bonding:mechanism and application in gas sensing[J].Polymers,2017,9(10):1-14.
[25]黄彬,江奇,谢德钰,等.模板法制备聚苯胺空心微球材料及其电化学性能[J].功能材料,2011,42(1):144-147.HUANG Bin,JIANG Qi,XIE De-yu,et al.Preparation of polyaniline hollow microsphere materials by template method and its electrochemical performance[J].Functional materials,2011,42(1):144-147.
[26]ELKAIS A R,GVOZDENOVIC M M,JUGOVIC B Z,et al.Electrochemical synthesis and characterization of polyaniline thin film and polyaniline powder[J].Progress in organic coatings,2011,71(1):32-35.
[27]佟威,郝建军,安成强,等.掺杂稀土铈对电化学合成聚苯胺膜耐蚀性的影响[J].电镀与精饰,2016,38(4):36-39.TONG Wei,HAO Jian-jun,AN Cheng-qiang,et al.Corrosion resistance of cerium doped PANI coatings prepared by electrochemical synthesis[J].Plating&finishing,2016,38(4):36-39.
[28]王华,宋航.铝表面聚苯胺的电化学合成与性能研究[J].表面技术,2016,45(4):46-52.WANG Hua,SONG Hang.Electrochemical synthesis and performance of polyaniline on aluminum surface[J].Surface technology,2016,45(4):46-52.
[29]OZYLLMAZ A T.The corrosion performance of polyaniline film modified on nickel plated copper in aqueous p-toluenesulfonic acid solution[J].Surface&coatings technology,2006,200(12-13):3918-3925.
[30]NICHO M E,HAILIN H U,GONZALEZ J G,et al.Protection of stainless steel by polyaniline films against corrosion in aqueous environments[J].Journal of applied electrochemistry,2006,36(2):153-160.
[31]徐远,谭德新,程小飞,等.酸掺杂聚苯胺合成及性能研究[J].化工新型材料,2017(11):69-72.XU Yuan,TAN De-xin,CHENG Xiao-fei,et al.Synthesis and properties of proton acid polyaniline[J].New chemical materials,2017(11):69-72.
[32]杨盈,李小宝,附青山,等.盐酸掺杂聚苯胺/炭黑作填料的导电涂料制备及其防腐蚀性能研究[J].涂料工业,2016,46(4):23-28.YANG Ying,LI Xiao-bao,FU Qing-shan,et al.Preparation and anticorrosive properties of conductive coatings based on HCl-doped polyaniline and carbon black as fillers[J].Coating industry,2016,46(4):23-28.
[33]王志强,杨小刚,孙瑞雪,等.酒石酸掺杂聚苯胺纳米纤维的制备及性能研究[J].高分子通报,2015(6):37-43.WANG Zhi-qiang,YANG Xiao-gang,SUN Rui-xue,et al.Preparation and properties of tartaric acid doped polyaniline nanofibers[J].Polymer bulletin,2015(6):37-43.
[34]刘春宁,李学强.酒石酸掺杂微/纳米结构聚苯胺的制备及表征[J].高分子材料科学与工程,2014,30(10):149-153.LIU Chun-ning,LI Xue-qiang.Synthesis and characterization of polyaniline micro/nanostructures doped with tartaric acid[J].Polymer materials science and engineering,2014,30(10):149-153.
[35]贾艺凡,刘朝辉,廖梓珺,等.十二烷基苯磺酸二次掺杂聚苯胺/环氧有机硅复合涂层的防腐性能[J].功能材料,2016,47(10):10138-10141.JIA Yi-fan,LIU Chao-hui,LIAO Zi-jun,et al.Anti-corrosion performance of dodecylbenzenesulfonate acid redoping polyaniline/epoxy-silicone composite coatings[J].Functional materials,2016,47(10):10138-10141.
[36]邓子悦,白盼星,王师霞,等.自分散聚苯胺/聚丙烯酸复合水性涂料的制备及其防腐蚀性能研究[J].现代化工,2016(3):107-110.DENG Zi-yue,BAI Pan-xing,WANG Shi-xia,et al.Preparation and anti-corrosion properties of self-dispersed polyaniline/polyacrylic waterborne composite coatings[J].Modern chemical industry,2016(3):107-110.
[37]叶文虎,钱浩,林志勇.混合酸(钠)制备高导电性?高分散性聚苯胺[J].化学工程与装备,2012(5):13-15.YE Wen-hu,QIAN Hao,LIN Zhi-yong.Mixed acid(sodium)for preparing highly conductive,highly dispersible polyaniline[J].Chemical engineering and equipment,2012(5):13-15.
[38]杨小刚,张国兵,王志强,等.单宁酸二次掺杂聚苯胺纳米材料的制备及防腐性能[J].高分子材料科学与工程,2017(9):120-125.YANG Xiao-gang,ZHANG Guo-bing,WANG Zhi-qiang,et al.Preparation and anti-corrosion properties of polyaniline secondary doped with tannic acid[J].Polymer materials science and engineering,2017(9):120-125.
[39]邢翠娟,于良民,张志明.超疏水性聚苯胺微/纳米结构的合成及防腐蚀性能[J].高等学校化学学报,2013,34(8):1999-2004.XING Cui-juan,YU Liang-min,ZHANG Zhi-ming.Superhydrophobic polyaniline micro/nano structures as anticorrosion coating[J].Chemical journal of Chinese universities,2013,34(8):1999-2004.
[40]侯婧莉,沈一丁,王海花,等.苯胺-对苯二胺共聚物改性水性聚氨酯-丙烯酸酯涂层的制备及防腐性能研究[J].功能材料,2017,48(1):1078-1083.HOU Liang-li,SHEN Yi-ding,WANG Hai-hua,et al.Study on the preparation and anticorrosion of waterborne polyurethane-acrylate coating modified by P-phenylenediamine-aniline[J].Functional materials,2017,48(1):1078-1083.
[41]王海花,王雪,费贵强.间氨基苯磺酸共聚改性聚苯胺的合成及性能研究[J].科学技术与工程,2016,16(27):65-69.WANG Hai-hua,WANG Xue,FEI Gui-qiang.Synthesis and performance of polyaniline copolymerized with3-aminobenzenesulfonic acid[J].Science technology and engineering,2016,16(27):65-69.
[42]SAZOU D,DESHPANDE P P.Conducting polyaniline nanocomposite-based paints for corrosion protection of steel[J].Chemical papers,2017,71(2):459-487.
[43]陈楠,刘薇娜.银表面聚苯胺/聚吡咯复合膜的制备及其耐蚀性[J].腐蚀与防护,2017,38(12):924-927.CHEN Nan,LIU Wei-na.Preparation and corrosion resistance of PANI/PPY composite films on sliver surface[J].Corrosion and protection,2017,38(12):924-927.
[44]CALDONA E B,DE LEON A C C,PAJARITO B B,et al.Novel anti-corrosion coatings from rubber-modified polybenzoxazine-based polyaniline composites[J].Applied surface science,2017,422:162-171.
[45]李玉峰,祝晶晶,高晓辉.水聚苯胺/叔氟丙烯酸酯复合防腐涂层的制备及性能[J].复合材料学报,2016,33(9):1859-1867.LI Yu-feng,ZHU Jing-jing,GAO Xiao-hui.Preparation and properties of waterborne polyaniline/versatate-fluoroacrylate composite anticorrosion coatings[J].Journal of composites,2016,33(9):1859-1867.
[46]徐惠,赵泽婷,刘嘉悦,等.表面活性剂改性超疏水聚苯胺的制备及防腐性能[J].高分子材料科学与工程,2016,32(10):89-93.XU Hui,ZHAO Ze-ting,LIU Jia-yue,et al.Facile fabrication of superhydrophobic polyaniline and their corrosion protection performance[J].Polymer materials science and engineering,2016,32(10):89-93.
[47]李振柱,雷亚红,吴荣,等.水性聚氨酯/聚苯胺导电防腐蚀涂料的研制[J].材料保护,2015,48(9):11-13.LI Zhen-zhu,LEI Ya-hong,WU Rong,et al.Development of water-borne polyurethane/polyaniline conductive anticorrosion coating[J].Material protection,2015,48(9):11-13.
[48]牟世辉,林雪,郝建军.电化学合成氧化钴/聚苯胺复合膜工艺研究[J].电镀与精饰,2018,40(3):22-25.MOU Shi-hui,LIN Xue,HAO Jian-jun.Electrochemical study on electrochemical synthesis of cobalt oxide/polyaniline composite film[J].Plating&finishing,2018,40(3):22-25.
[49]郑媛,罗静,魏玮,等.Pickering乳液法制备聚苯胺-石墨烯空心微球[J].化学学报,2017,75(4):391-397.ZHENG Yuan,LUO Jing,WEI Wei,et al.Polyaniline-graphene hollow spheres based on graphene stabilized pickering emulsions[J].Acta chemical,2017,75(4):391-397.
[50]李俊,郑豪.聚苯胺蒙脱石纳米复合材料的防腐蚀性能[J].材料保护,2016,49(9):69-73.LI Jun,ZHENG Hao.Corrosion resistance of polyaniline montmorillonite nanocomposites[J].Material protection,2016,49(9):69-73.
[51]RADHAKRISHNAN S,SIJU C R,MAHANTA D,et al.Conducting polyaniline-nano-TiO2,composites for smart corrosion resistant coatings[J].Electrochimica acta,2009,54(4):1249-1254.
[52]JAFARI Y,GHOREISHI S M,SHABANI-NOOSHABADIM.Polyaniline/graphene nanocomposite coatings on copper:Electropolymerization,characterization,and evaluation of corrosion protection performance[J].Synthetic metals,2016,217:220-230.
[53]TIAN Z,YU H,WANG L,et al.Cheminform abstract:Recent progress in the preparation of polyaniline nanostructures and their applications in anticorrosive coatings[J].RSC advances,2015,45(46):28195-28208.
[54]宋世红.掺聚苯胺纳米纤维的水性环氧树脂涂料的防腐性能研究[J].塑料工业,2017(12):143-146.SONG Shi-hong.Study on anticorrosive properties of waterborne epoxy resin doped with polyaniline nanofibers[J].Plastics industry,2017(12):143-146.
[55]宋哲,张婧坤,李晓飞,等.聚苯胺防腐粉末涂料的制备及性能研究[J].化工新型材料,2018(1):89-92.SONG Zhe,ZHANG Jing-kun,LI Xiao-fei,et al.Preparation and characterization of polyaniline powder coating for anticorrosion[J].New chemical materials,2018(1):89-92.
[56]张兰河,李尧松,王冬,等.聚苯胺/石墨烯水性涂料的制备及其防腐性能研究[J].中国电机工程学报,2015,35(S1):170-176.ZHANG Lan-he,LI Yao-song,WANG Dong,et al.Preparation and anticorrosion performance of polyaniline/graphene waterborne coatings[J].Journal of electrical engineering of China,2015,35(S1):170-176.
[57]QIU S,CHEN C,ZHENG W,et al.Long-term corrosion protection of mild steel by epoxy coating containing self-doped polyaniline nanofiber[J].Synthetic metals,2017,229:39-46.
[58]夏继军,史智昊,黄艺.纳米聚苯胺/磷酸锌/聚硅氧烷复合涂层自修复和耐蚀性能研究[J].中国有色冶金,2017,46(3):77-80.XIA Ji-Jun,SHI Zhi-hao,HUANG Yi.Self-healing and corrosion resistant properties of nano-polyaniline/zinc phosphate/polysiloxane compound coating[J].China nonferrous metals,2017,46(3):77-80.
[59]HOU X,WANG Y,SUN G,et al.Effect of polyaniline-modified glass flakes on the corrosion protection properties of epoxy coatings[J].High performance polymers,2016,29(3):305-314.
[60]胡传波,厉英,孔亚州,等.聚邻氯苯胺-纳米Si C/环氧树脂复合材料的制备与防腐性能[J].复合材料学报,2017,34(6):1167-1176.HU Chuan-bo,LI Ying,KONG Ya-zhou,et al.Preparation and corrosion resistance of poly(o-chloroaniline)-nano-SiC/epoxy composites[J].Journal of composites,2017,34(6):1167-1176.
[2]程佳,孙锦辉,杜猛.对金属材料的腐蚀与防护分析[J].中国科技投资,2016(9):187.CHENG Jia,SUN Jin-hui,DU Meng.Analysis of corrosion and protection of metal materials[J].China science and technology investment,2016(9):187.
[3]NAZEER A A,MADKOUR M.Potential use of smart coatings for corrosion protection of metals and alloys:Areview[J].Journal of molecular liquids,2018,253:11-22.
[4]刘永超,赵雄燕,王鑫,等.防腐涂料的研究进展[J].化工新型材料,2016(4):38-40.LIU Yong-chao,ZHAO Xiong-yan,WANG Xin,et al.Research progress of anticorrosion coatings[J].New chemical materials,2016(4):38-40.
[5]王霞,唐佳,陈玉祥,等.流速对L360管线钢在H2S/CO2环境中腐蚀行为的影响[J].表面技术,2018,47(2):157-163.WANG Xia,TANG Jia,CHEN Yu-xiang,et al.Effect of flow velocity on corrosion behavior of L360 pipeline steel in H2S/CO2 environment[J].Surface technology,2018,47(2):157-163.
[6]KOHL M,KALENDOVA A,CERNOSKOVA E,et al.Corrosion protection by organic coatings containing polyaniline salts prepared by oxidative polymerization[J].Journal of coatings technology&research,2017,14(6):1-14.
[7]LI Z,SHEN Y,LI Y,et al.Doping effects of cerium ion on structure and electrochemical properties of polyaniline[J].Polymer international,2018,67(1):121-126.
[8]KURBATOV V G,INDEIKIN E A.Anticorrosion pigments with a shell of doped polyaniline[J].Protection of metals&physical chemistry of surfaces,2017,53(2):329-334.
[9]ZHANG Y,SHAO Y,LIU X,et al.A study on corrosion protection of different polyaniline coatings for mild steel[J].Progress in organic coatings,2017,111:240-247.
[10]CALDONA E B,DE LEON A C C,PAJARITO B B,et al.Novel anti-corrosion coatings from rubber-modified polybenzoxazine-based polyaniline composites[J].Applied surface science,2017,422:162-171.
[11]LIAO Z J,LIN C X,YANG C J,et al.Study on the preparation and electrochemical properties of nano ZnO/polyaniline composite anticorrosive coating[C]//Proceedings of the 2016 international conference on advances in energy,environment and chemical science,[s.l]:Atlantis Press,2016,76:294-298.
[12]DEBERRY D W.Modification of the electrochemical and corrosion behavior of stainless steels with an electroactive coating[J].Chem inform,1985,16(37):917-926.
[13]张静,冯玉坤,万小梅,等.导电聚苯胺的制备及其在防腐涂料中的应用[J].现代涂料与涂装,2011,14(3):12-14.ZHANG Jing,FENG Yu-kun,WAN Xiao-mei,et al.Preparation of conductive polyaniline and its application in anti-corrosion coatings[J].Modern coatings&coating,2011,14(3):12-14.
[14]HAFIZAH M A E,BIMANTORO A,ANDREAS,et al.Synthesized of conductive polyaniline by solution polymerization technique[J].Procedia chemistry,2016,19:162-165.
[15]夏小倩,沈玉芳,郭文勇,等.乳液聚合法合成聚苯胺材料进展[J].甘肃石油和化工,2010,24(4):1-5.XIA Xiao-qian,SHEN Yu-fang,GUO Wen-yong,et al.Progress in the synthesis of polyaniline materials by emulsion polymerization[J].Gansu petroleum&chemical industry,2010,24(4):1-5.
[16]WU Y J,HO K S,CHENG Y W,et al.Studies on the synthesis of low molecular weight,one-dimensional polyanilines prepared by fast emulsion polymerization using HCl/(n-Dodecylbenzenesulfonic acid)emulsifiers[J].Polymer international,2013,62(4):581-590.
[17]WANG Y,CHEN K,LI T,et al.Soluble polyaniline nanofibers prepared via surfactant-free emulsion polymerization[J].Synthetic metals,2014,198:293-299.
[18]PERRIN F X,PHAN T A,NGUYEN D L.Synthesis and characterization of polyaniline nanoparticles in phosphonic acid amphiphile aqueous micellar solutions for waterborne corrosion protection coatings[J].Journal of polymer science part A:Polymer chemistry,2015,53(13):1606-1616.
[19]ZHOU H H,FANG C X,YE T T,et al.Electrochemical synthesis of polyaniline in reverse microemulsion[J].Journal of Central South University,2014,21(11):4071-4075.
[20]ULLAH R,BILAL S,SHAH A U H A,et al.Synthesis and characterization of polyaniline doped with polyvinyl alcohol by inverse emulsion polymerization[J].Synthetic metals,2016,222:162-169.
[21]WANG X Y,LIU C Y,MIAO L,et al.Improving the thermoelectric properties of polyaniline by introducing poly(3,4-ethylenedioxythiophene)[J].Journal of electronic materials,2016,45(3):1813-1820.
[22]王国祥,刘鹏丽.反相微乳液聚合法合成聚苯胺[J].合成树脂及塑料,2011,28(2):23-26.WANG Guo-xiang,LIU Peng-li.Synthesis of polyaniline by reverse microemulsion polymerization[J].Synthetic resins&plastics,2011,28(2):23-26.
[23]GORDANA C M.Recent advances in polyaniline research:Polymerization mechanisms,structural aspects,properties and applications[J].Synthetic metals,2013,177:1-47.
[24]YIN C,GAO L,ZHOU F,et al.Facile synthesis of polyaniline nanotubes using self-assembly method based on the hydrogen bonding:mechanism and application in gas sensing[J].Polymers,2017,9(10):1-14.
[25]黄彬,江奇,谢德钰,等.模板法制备聚苯胺空心微球材料及其电化学性能[J].功能材料,2011,42(1):144-147.HUANG Bin,JIANG Qi,XIE De-yu,et al.Preparation of polyaniline hollow microsphere materials by template method and its electrochemical performance[J].Functional materials,2011,42(1):144-147.
[26]ELKAIS A R,GVOZDENOVIC M M,JUGOVIC B Z,et al.Electrochemical synthesis and characterization of polyaniline thin film and polyaniline powder[J].Progress in organic coatings,2011,71(1):32-35.
[27]佟威,郝建军,安成强,等.掺杂稀土铈对电化学合成聚苯胺膜耐蚀性的影响[J].电镀与精饰,2016,38(4):36-39.TONG Wei,HAO Jian-jun,AN Cheng-qiang,et al.Corrosion resistance of cerium doped PANI coatings prepared by electrochemical synthesis[J].Plating&finishing,2016,38(4):36-39.
[28]王华,宋航.铝表面聚苯胺的电化学合成与性能研究[J].表面技术,2016,45(4):46-52.WANG Hua,SONG Hang.Electrochemical synthesis and performance of polyaniline on aluminum surface[J].Surface technology,2016,45(4):46-52.
[29]OZYLLMAZ A T.The corrosion performance of polyaniline film modified on nickel plated copper in aqueous p-toluenesulfonic acid solution[J].Surface&coatings technology,2006,200(12-13):3918-3925.
[30]NICHO M E,HAILIN H U,GONZALEZ J G,et al.Protection of stainless steel by polyaniline films against corrosion in aqueous environments[J].Journal of applied electrochemistry,2006,36(2):153-160.
[31]徐远,谭德新,程小飞,等.酸掺杂聚苯胺合成及性能研究[J].化工新型材料,2017(11):69-72.XU Yuan,TAN De-xin,CHENG Xiao-fei,et al.Synthesis and properties of proton acid polyaniline[J].New chemical materials,2017(11):69-72.
[32]杨盈,李小宝,附青山,等.盐酸掺杂聚苯胺/炭黑作填料的导电涂料制备及其防腐蚀性能研究[J].涂料工业,2016,46(4):23-28.YANG Ying,LI Xiao-bao,FU Qing-shan,et al.Preparation and anticorrosive properties of conductive coatings based on HCl-doped polyaniline and carbon black as fillers[J].Coating industry,2016,46(4):23-28.
[33]王志强,杨小刚,孙瑞雪,等.酒石酸掺杂聚苯胺纳米纤维的制备及性能研究[J].高分子通报,2015(6):37-43.WANG Zhi-qiang,YANG Xiao-gang,SUN Rui-xue,et al.Preparation and properties of tartaric acid doped polyaniline nanofibers[J].Polymer bulletin,2015(6):37-43.
[34]刘春宁,李学强.酒石酸掺杂微/纳米结构聚苯胺的制备及表征[J].高分子材料科学与工程,2014,30(10):149-153.LIU Chun-ning,LI Xue-qiang.Synthesis and characterization of polyaniline micro/nanostructures doped with tartaric acid[J].Polymer materials science and engineering,2014,30(10):149-153.
[35]贾艺凡,刘朝辉,廖梓珺,等.十二烷基苯磺酸二次掺杂聚苯胺/环氧有机硅复合涂层的防腐性能[J].功能材料,2016,47(10):10138-10141.JIA Yi-fan,LIU Chao-hui,LIAO Zi-jun,et al.Anti-corrosion performance of dodecylbenzenesulfonate acid redoping polyaniline/epoxy-silicone composite coatings[J].Functional materials,2016,47(10):10138-10141.
[36]邓子悦,白盼星,王师霞,等.自分散聚苯胺/聚丙烯酸复合水性涂料的制备及其防腐蚀性能研究[J].现代化工,2016(3):107-110.DENG Zi-yue,BAI Pan-xing,WANG Shi-xia,et al.Preparation and anti-corrosion properties of self-dispersed polyaniline/polyacrylic waterborne composite coatings[J].Modern chemical industry,2016(3):107-110.
[37]叶文虎,钱浩,林志勇.混合酸(钠)制备高导电性?高分散性聚苯胺[J].化学工程与装备,2012(5):13-15.YE Wen-hu,QIAN Hao,LIN Zhi-yong.Mixed acid(sodium)for preparing highly conductive,highly dispersible polyaniline[J].Chemical engineering and equipment,2012(5):13-15.
[38]杨小刚,张国兵,王志强,等.单宁酸二次掺杂聚苯胺纳米材料的制备及防腐性能[J].高分子材料科学与工程,2017(9):120-125.YANG Xiao-gang,ZHANG Guo-bing,WANG Zhi-qiang,et al.Preparation and anti-corrosion properties of polyaniline secondary doped with tannic acid[J].Polymer materials science and engineering,2017(9):120-125.
[39]邢翠娟,于良民,张志明.超疏水性聚苯胺微/纳米结构的合成及防腐蚀性能[J].高等学校化学学报,2013,34(8):1999-2004.XING Cui-juan,YU Liang-min,ZHANG Zhi-ming.Superhydrophobic polyaniline micro/nano structures as anticorrosion coating[J].Chemical journal of Chinese universities,2013,34(8):1999-2004.
[40]侯婧莉,沈一丁,王海花,等.苯胺-对苯二胺共聚物改性水性聚氨酯-丙烯酸酯涂层的制备及防腐性能研究[J].功能材料,2017,48(1):1078-1083.HOU Liang-li,SHEN Yi-ding,WANG Hai-hua,et al.Study on the preparation and anticorrosion of waterborne polyurethane-acrylate coating modified by P-phenylenediamine-aniline[J].Functional materials,2017,48(1):1078-1083.
[41]王海花,王雪,费贵强.间氨基苯磺酸共聚改性聚苯胺的合成及性能研究[J].科学技术与工程,2016,16(27):65-69.WANG Hai-hua,WANG Xue,FEI Gui-qiang.Synthesis and performance of polyaniline copolymerized with3-aminobenzenesulfonic acid[J].Science technology and engineering,2016,16(27):65-69.
[42]SAZOU D,DESHPANDE P P.Conducting polyaniline nanocomposite-based paints for corrosion protection of steel[J].Chemical papers,2017,71(2):459-487.
[43]陈楠,刘薇娜.银表面聚苯胺/聚吡咯复合膜的制备及其耐蚀性[J].腐蚀与防护,2017,38(12):924-927.CHEN Nan,LIU Wei-na.Preparation and corrosion resistance of PANI/PPY composite films on sliver surface[J].Corrosion and protection,2017,38(12):924-927.
[44]CALDONA E B,DE LEON A C C,PAJARITO B B,et al.Novel anti-corrosion coatings from rubber-modified polybenzoxazine-based polyaniline composites[J].Applied surface science,2017,422:162-171.
[45]李玉峰,祝晶晶,高晓辉.水聚苯胺/叔氟丙烯酸酯复合防腐涂层的制备及性能[J].复合材料学报,2016,33(9):1859-1867.LI Yu-feng,ZHU Jing-jing,GAO Xiao-hui.Preparation and properties of waterborne polyaniline/versatate-fluoroacrylate composite anticorrosion coatings[J].Journal of composites,2016,33(9):1859-1867.
[46]徐惠,赵泽婷,刘嘉悦,等.表面活性剂改性超疏水聚苯胺的制备及防腐性能[J].高分子材料科学与工程,2016,32(10):89-93.XU Hui,ZHAO Ze-ting,LIU Jia-yue,et al.Facile fabrication of superhydrophobic polyaniline and their corrosion protection performance[J].Polymer materials science and engineering,2016,32(10):89-93.
[47]李振柱,雷亚红,吴荣,等.水性聚氨酯/聚苯胺导电防腐蚀涂料的研制[J].材料保护,2015,48(9):11-13.LI Zhen-zhu,LEI Ya-hong,WU Rong,et al.Development of water-borne polyurethane/polyaniline conductive anticorrosion coating[J].Material protection,2015,48(9):11-13.
[48]牟世辉,林雪,郝建军.电化学合成氧化钴/聚苯胺复合膜工艺研究[J].电镀与精饰,2018,40(3):22-25.MOU Shi-hui,LIN Xue,HAO Jian-jun.Electrochemical study on electrochemical synthesis of cobalt oxide/polyaniline composite film[J].Plating&finishing,2018,40(3):22-25.
[49]郑媛,罗静,魏玮,等.Pickering乳液法制备聚苯胺-石墨烯空心微球[J].化学学报,2017,75(4):391-397.ZHENG Yuan,LUO Jing,WEI Wei,et al.Polyaniline-graphene hollow spheres based on graphene stabilized pickering emulsions[J].Acta chemical,2017,75(4):391-397.
[50]李俊,郑豪.聚苯胺蒙脱石纳米复合材料的防腐蚀性能[J].材料保护,2016,49(9):69-73.LI Jun,ZHENG Hao.Corrosion resistance of polyaniline montmorillonite nanocomposites[J].Material protection,2016,49(9):69-73.
[51]RADHAKRISHNAN S,SIJU C R,MAHANTA D,et al.Conducting polyaniline-nano-TiO2,composites for smart corrosion resistant coatings[J].Electrochimica acta,2009,54(4):1249-1254.
[52]JAFARI Y,GHOREISHI S M,SHABANI-NOOSHABADIM.Polyaniline/graphene nanocomposite coatings on copper:Electropolymerization,characterization,and evaluation of corrosion protection performance[J].Synthetic metals,2016,217:220-230.
[53]TIAN Z,YU H,WANG L,et al.Cheminform abstract:Recent progress in the preparation of polyaniline nanostructures and their applications in anticorrosive coatings[J].RSC advances,2015,45(46):28195-28208.
[54]宋世红.掺聚苯胺纳米纤维的水性环氧树脂涂料的防腐性能研究[J].塑料工业,2017(12):143-146.SONG Shi-hong.Study on anticorrosive properties of waterborne epoxy resin doped with polyaniline nanofibers[J].Plastics industry,2017(12):143-146.
[55]宋哲,张婧坤,李晓飞,等.聚苯胺防腐粉末涂料的制备及性能研究[J].化工新型材料,2018(1):89-92.SONG Zhe,ZHANG Jing-kun,LI Xiao-fei,et al.Preparation and characterization of polyaniline powder coating for anticorrosion[J].New chemical materials,2018(1):89-92.
[56]张兰河,李尧松,王冬,等.聚苯胺/石墨烯水性涂料的制备及其防腐性能研究[J].中国电机工程学报,2015,35(S1):170-176.ZHANG Lan-he,LI Yao-song,WANG Dong,et al.Preparation and anticorrosion performance of polyaniline/graphene waterborne coatings[J].Journal of electrical engineering of China,2015,35(S1):170-176.
[57]QIU S,CHEN C,ZHENG W,et al.Long-term corrosion protection of mild steel by epoxy coating containing self-doped polyaniline nanofiber[J].Synthetic metals,2017,229:39-46.
[58]夏继军,史智昊,黄艺.纳米聚苯胺/磷酸锌/聚硅氧烷复合涂层自修复和耐蚀性能研究[J].中国有色冶金,2017,46(3):77-80.XIA Ji-Jun,SHI Zhi-hao,HUANG Yi.Self-healing and corrosion resistant properties of nano-polyaniline/zinc phosphate/polysiloxane compound coating[J].China nonferrous metals,2017,46(3):77-80.
[59]HOU X,WANG Y,SUN G,et al.Effect of polyaniline-modified glass flakes on the corrosion protection properties of epoxy coatings[J].High performance polymers,2016,29(3):305-314.
[60]胡传波,厉英,孔亚州,等.聚邻氯苯胺-纳米Si C/环氧树脂复合材料的制备与防腐性能[J].复合材料学报,2017,34(6):1167-1176.HU Chuan-bo,LI Ying,KONG Ya-zhou,et al.Preparation and corrosion resistance of poly(o-chloroaniline)-nano-SiC/epoxy composites[J].Journal of composites,2017,34(6):1167-1176.