CoCrMoW合金的粉末特性及其激光选区熔化成形性能
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摘要
利用真空气雾化技术制备激光选区熔化成形用CoCrMoW合金粉末,检测分析了粉末的特性,引入椭圆延伸度、ISO圆度、赘生物指数来定量表征粉末的粒形和卫星粉,并研究了该粉末的SLM成形性能和电化学性能。结果表明:粉末的D10、D50、D90粒度分别为:12.50、28.71、58.05μm;大部分粉末在形状上为球形和近球形,粉末平均椭圆延伸度为0.212,平均ISO圆度为0.607,表面没有粘连微粒的粉末占总体积的74.89%;粉末的松装密度为4.82 g/cm~3,振实密度为5.71 g/cm~3,压缩度为15.6%。粉末适用于激光选区熔化成形,成形试样致密度达到98.7%,表面粗糙度为8.3μm;显微硬度(HV)为3960 MPa,抗拉强度为1154 MPa,屈服强度为852 MPa,延伸率为8.5%,且耐腐蚀性能优于铸造CoCr合金。
CoCrMoW alloy powder for 3 D printing was prepared by vacuum gas atomization. Particle characteristics were studied and the Ell.Elongation, ISO Circularity and Outgrowth were introduced to characterize the particle shape. And the Selective Laser Melting(SLM)forming properties of the powders and electrochemical properties of the formed parts were studied. The results indicate that the measured D10, D50 and D90 are 12.50, 28.71 and 58.05 μm, respectively. The majority of powder particles are spherical or nearly spherical and the mean Ell.Elongation and ISO Circularity are 0.212 and 0.607, respectively. About 74.89% of the powder particles have no adhesion on the surface. The apparent density and tap density are 4.82 and 5.71 g/cm3, respectively, and the compressibility is 15.6%. The CoCrMoW powder is suitable for SLM and the relative density and surface roughness are 98.7% and 8.3 μm, respectively. The microhardness(HV),tensile strength, yield strength and elongation are 3960 MPa, 1154 MPa, 852 MPa and 8.5%, respectively. And the corrosion resistance of CoCrMoW alloy prepared by SLM is better than that of the cast alloy.
CoCrMoW alloy powder for 3 D printing was prepared by vacuum gas atomization. Particle characteristics were studied and the Ell.Elongation, ISO Circularity and Outgrowth were introduced to characterize the particle shape. And the Selective Laser Melting(SLM)forming properties of the powders and electrochemical properties of the formed parts were studied. The results indicate that the measured D10, D50 and D90 are 12.50, 28.71 and 58.05 μm, respectively. The majority of powder particles are spherical or nearly spherical and the mean Ell.Elongation and ISO Circularity are 0.212 and 0.607, respectively. About 74.89% of the powder particles have no adhesion on the surface. The apparent density and tap density are 4.82 and 5.71 g/cm3, respectively, and the compressibility is 15.6%. The CoCrMoW powder is suitable for SLM and the relative density and surface roughness are 98.7% and 8.3 μm, respectively. The microhardness(HV),tensile strength, yield strength and elongation are 3960 MPa, 1154 MPa, 852 MPa and 8.5%, respectively. And the corrosion resistance of CoCrMoW alloy prepared by SLM is better than that of the cast alloy.
引文
[1] Su Haijun(苏海军),Wei Kaichen(尉凯晨),Guo Wei(郭伟)et al. The Chinese Journal of Nonferrous Metals(中国有色金属学报)[J],2013(6):1567
[2] Mumtaz K A, Erasenthiran P,Hopkinson N. Journal of Materials Processing Technology[J], 2008, 195(1-3):77
[3] Demir A G, Monguzzi L, Previtali B. Additive Manufacturing[J], 2017,15:20
[4] Zeng Guang(曾光),Han Zhiyu(韩志宇),Liang Shujin(梁书锦)et al. Materials China(中国材料进展)[J], 2014(6):376
[5] Takaichi A, Suyalatu, Nakamoto T et al. Journal of the Mechanical Behavior of Biomedical Materials[J], 2013,21(3):67
[6] Schwindling F S, Seubert M, Rues S et al. Tribology Letters[J], 2015, 60(2):25
[7] Demir A G, Previtali B. Materials&Design[J], 2017, 119:338
[8] Xin X Z, Xiang N, Chen J et al. Materials Letters[J], 2012,88(8):101
[9] Xin X Z, Chen J, Xiang N et al. Dental Materials[J], 2014,30(3):263
[10] Matkovic T, Matkovic P, Malina J. Journal of Alloys and Compounds[J], 2004, 366(1-2):293
[11] Wu Zhikai(吴芝凯),Li Ning(李宁). Special Casting and Nonferrous Alloys(特种铸造及有色合金)[J],2011,31(2):164
[12] Ozbilen S. Powder Metallurgy[J], 1999, 42(1):70
[13] The United States Pharmacopeial Convention. US Patent,29-NF 24[P]. 2006
[14] Wang Liang(王亮),Pan Jing(潘静),Yuan Ying(袁颖)et al. China Powder Science and Technology(中国粉体技术)[J], 2016(5):28
[15] Liu Zhi(刘治),Lv Xiaowei(吕晓卫),Zhang Chunbao(张春宝)et al. Journal of Practical Stomatology(实用口腔医学杂志)[J],2010, 26(4):433
[2] Mumtaz K A, Erasenthiran P,Hopkinson N. Journal of Materials Processing Technology[J], 2008, 195(1-3):77
[3] Demir A G, Monguzzi L, Previtali B. Additive Manufacturing[J], 2017,15:20
[4] Zeng Guang(曾光),Han Zhiyu(韩志宇),Liang Shujin(梁书锦)et al. Materials China(中国材料进展)[J], 2014(6):376
[5] Takaichi A, Suyalatu, Nakamoto T et al. Journal of the Mechanical Behavior of Biomedical Materials[J], 2013,21(3):67
[6] Schwindling F S, Seubert M, Rues S et al. Tribology Letters[J], 2015, 60(2):25
[7] Demir A G, Previtali B. Materials&Design[J], 2017, 119:338
[8] Xin X Z, Xiang N, Chen J et al. Materials Letters[J], 2012,88(8):101
[9] Xin X Z, Chen J, Xiang N et al. Dental Materials[J], 2014,30(3):263
[10] Matkovic T, Matkovic P, Malina J. Journal of Alloys and Compounds[J], 2004, 366(1-2):293
[11] Wu Zhikai(吴芝凯),Li Ning(李宁). Special Casting and Nonferrous Alloys(特种铸造及有色合金)[J],2011,31(2):164
[12] Ozbilen S. Powder Metallurgy[J], 1999, 42(1):70
[13] The United States Pharmacopeial Convention. US Patent,29-NF 24[P]. 2006
[14] Wang Liang(王亮),Pan Jing(潘静),Yuan Ying(袁颖)et al. China Powder Science and Technology(中国粉体技术)[J], 2016(5):28
[15] Liu Zhi(刘治),Lv Xiaowei(吕晓卫),Zhang Chunbao(张春宝)et al. Journal of Practical Stomatology(实用口腔医学杂志)[J],2010, 26(4):433