硬质合金切削刀具研究进展
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摘要
本文综述了铁族硬质合金的性能特点,重点关注了WC-Co基硬质合金的研究现状,归纳了通过添加不同组分对硬质合金性能的影响,介绍了粉体制备、烧结工艺、制备过程中的相变以及界面反应,指出WC/Co薄层界面相容的晶格匹配使其表现出优良的服役性能。然而,高速切削对硬质合金刀具的强度、硬度、耐磨性和高温抗氧化性等各项性能提出了新的挑战,新型硬质合金的开发仍然任重而道远。
The performance characteristics of iron-based cemented carbides are reviewed, especially concerning on the state-of the-art of WC-Co-based cemented carbides. The effects of different components on the properties of cemented carbides are summarized, and the powder preparation, sintering process, phase transformation in the preparation process and interfacial reaction are introduced. It is pointed out that the lattice matching of WC/Co thin layer interface makes it show excellent service performance. However, high-speed cutting poses new challenges to the properties of cemented carbide tools such as strength, hardness, wear resistance and high-temperature oxidation resistance, the development of new cemented carbides still has a long way to go.
The performance characteristics of iron-based cemented carbides are reviewed, especially concerning on the state-of the-art of WC-Co-based cemented carbides. The effects of different components on the properties of cemented carbides are summarized, and the powder preparation, sintering process, phase transformation in the preparation process and interfacial reaction are introduced. It is pointed out that the lattice matching of WC/Co thin layer interface makes it show excellent service performance. However, high-speed cutting poses new challenges to the properties of cemented carbide tools such as strength, hardness, wear resistance and high-temperature oxidation resistance, the development of new cemented carbides still has a long way to go.
引文
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2 Ortner H M,Ettmayer P,Kolaska H.International Journal of Refractory Metals and Hard Materials,2014,44,148.
3 Katiyar P K,Singh P K,Singh R,et al.International Journal of Refractory Metals and Hard Materials,2016,54,27.
4 Pervaiz S,Kannan S,Kishawy H.Journal of Cleaner Production,2018,197,134.
5 Goindi G S,Sarkar P.Journal of Cleaner Production,2017,165,1557.
6 Chen J,Yang J,Chen B,et al.Surface and Coatings Technology,2016,305,23.
7龙坚战,陆必志,易茂中,等.硬质合金,2015,32(3),204.
8 Abolaji R S,Bingxue Z,Anbalgam K,et al.Progress in Solid State Chemistry,2018,50,1.
9 Chicardi E,Bermejo R,Gotor F J,et al.International Journal of Refractory Metals and Hard Materials,2018,71,82.
10 Tarraste M,Kübarsepp J,Juhani K,et al.International Journal of Refractory Metals and Hard Materials,2018,73,183.
11 Mingard K P,Roebuck B,Marshall J,et al.Acta Materialia,2011,59(6),2277.
12 Toller L,Jacobson S,Norgren S.Wear,2017,376,1822.
13 Gao Y,Luo B H,He K J,et al.Ceramics International,2018,44(2),2030.
14黄道远.热/力作用下钴基硬质合金组织性能变化及相关机理的研究.博士学位论文,中南大学,2010.
15 Adorjan A,Schubert W D,Sch9n A,et al.International Journal of Refractory Metals and Hard Materials,2006,24(5),365.
16 Farag S,Konyashin I,Ries B.International Journal of Refractory Metals and Hard Materials,2018,77,12.
17 Soleimanpour A M,Abachi P,Simchi A.International Journal of Refractory Metals and Hard Materials,2012,31,141.
18王红彬.一步还原法制备(W-Ti-Ta-Nb)C复合碳化物的研究.硕士学位论文,中南大学,2009.
19 Li X,Liu Y,Wei W,et al.Materials&Design,2016,90,562.
20丁勇.一步法制备超细WC-Co基硬质合金的组织控制及性能.硕士学位论文,华南理工大学,2013.
21朱敏.华南理工大学学报(自然科学版),2002,30(11),89.
22王明超,赵志伟,杨德青,等.材料导报,2015,29(专辑25),26.
23 García J,Colladoés V,Blomqvist A,et al.International Journal of Refractory Metals and Hard Materials,2018,80,40.
24 Liu S,Huang Z L,Liu G,et al.International Journal of Refractory Metals&Hard Materials,2006,24(6),461.
25蔡惠坤,翁泽钜,顾开选,等.材料导报:综述篇,2019,33(1),175.
26尹福兰,丁国富,杨大治,等.金属热处理,2018,43(9),23.
27 Bounhoure V,Lay S,Loubradou M,et al.Journal of Materials Science,2008,43(3),892.
28 Konyashin I,Sologubenko A,Weirich T,et al.Materials Letters,2017,187,7.
29 Johansson S A E,Wahnstr9m G.Current Opinion in Solid State and Materials Science,2016,20(5),299.
30 Mingard K P,Roebuck B,Marshall J,et al.Acta Materialia,2011,59(6),2277.
31 Weidow J,Andrén H O.International Journal of Refractory Metals and Hard Materials,2011,29(1),38.
32 Garcia J.International Journal of Refractory Metals and Hard Materials,2012,30(1),114.
33 Andren H O.Materials Chemistry and Physics,2001,67(1-3),209.
34 Shatov A V,Firstov S A,Shatova I V.Materials Science and Engineering:A,1998,242(1-2),7.
35贺从训,毛昌辉,汪有明,等.硬质合金,1996,13(1),23.
36 Zhang L,Schubert W D,Huang B Y,et al.P/M Science&Technology Briefs,2003,5(3),17.
37 Xu C H,Ai X,Huang C Z,et al.Chinese Rare Earths,1997,18(3),55.
38 Chen B,Yang J,Zhang Q,et al.Materials&Design,2015,75,24.
39 Spear J C,Ewers B W,Batteas J D.Nano Today,2015,10(3),301.
40 Zhang X,Zhang D,Tang H,et al.Materials Research Bulletin,2014,53,96.
41 Chen J,Yang J,Chen B,et al.Surface and Coatings Technology,2016,305,23.